[(1R,4S)-3-Benzenesulfonyl-4-((E)-7-benzyloxy-2-methoxymethoxymethyl-hept-2-enyl)-cyclopent-2-enyloxy]-tert-butyl-diphenyl-silane

Base Information

Chemical Name:[(1R,4S)-3-Benzenesulfonyl-4-((E)-7-benzyloxy-2-methoxymethoxymethyl-hept-2-enyl)-cyclopent-2-enyloxy]-tert-butyl-diphenyl-silane
CAS No.:109124-96-1
Molecular Formula:C₄₄H₅₄O₆SSi
Molecular Weight:739.061
Hs Code.:

Synonyms:[(1R,4S)-3-Benzenesulfonyl-4-((E)-7-benzyloxy-2-methoxymethoxymethyl-hept-2-enyl)-cyclopent-2-enyloxy]-tert-butyl-diphenyl-silane

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Chemical Property of [(1R,4S)-3-Benzenesulfonyl-4-((E)-7-benzyloxy-2-methoxymethoxymethyl-hept-2-enyl)-cyclopent-2-enyloxy]-tert-butyl-diphenyl-silane

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Technology Process of [(1R,4S)-3-Benzenesulfonyl-4-((E)-7-benzyloxy-2-methoxymethoxymethyl-hept-2-enyl)-cyclopent-2-enyloxy]-tert-butyl-diphenyl-silane

There total 1 articles about [(1R,4S)-3-Benzenesulfonyl-4-((E)-7-benzyloxy-2-methoxymethoxymethyl-hept-2-enyl)-cyclopent-2-enyloxy]-tert-butyl-diphenyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₃₀H₃₈NO₃SSi⁽¹⁺⁾*BF₄^(1-)

: ((Z)-7-Benzyloxy-2-methoxymethoxymethyl-hept-2-enyl)-trimethyl-stannane

: 109124-96-1
[(1R,4S)-3-Benzenesulfonyl-4-((E)-7-benzyloxy-2-methoxymethoxymethyl-hept-2-enyl)-cyclopent-2-enyloxy]-tert-butyl-diphenyl-silane

Guidance literature:: Yield given. Multistep reaction;
DOI:10.1021/ja00249a068

Reference yield: 85.0%

: 109124-96-1
[(1R,4S)-3-Benzenesulfonyl-4-((E)-7-benzyloxy-2-methoxymethoxymethyl-hept-2-enyl)-cyclopent-2-enyloxy]-tert-butyl-diphenyl-silane

: 109124-97-2
(E)-2-[(1S,4R)-2-Benzenesulfonyl-4-(tert-butyl-diphenyl-silanyloxy)-cyclopent-2-enylmethyl]-7-benzyloxy-hept-2-en-1-ol

Guidance literature:: With dimethylboron bromide; In dichloromethane; at -78 ℃; for 1h;
DOI:10.1021/ja00249a068

Reference yield:

: 109124-96-1
[(1R,4S)-3-Benzenesulfonyl-4-((E)-7-benzyloxy-2-methoxymethoxymethyl-hept-2-enyl)-cyclopent-2-enyloxy]-tert-butyl-diphenyl-silane

: 109125-00-0
(1S,2R,3aS,6aR)-6a-Benzenesulfonyl-5-[5-benzyloxy-pent-(E)-ylidene]-1-((E)-(S)-3-hydroxy-oct-1-enyl)-octahydro-pentalen-2-ol

Guidance literature:: Multi-step reaction with 4 steps

1: 85 percent / dimethylboron bromide / CH₂Cl₂ / 1 h / -78 °C

2: 98 percent

3: 95 percent / tetrahydrofuran / 0.25 h / -78 °C / -50 deg C, 10 min

4: 80 percent / tetrabutylammonium fluoride / tetrahydrofuran / 24 h / 25 °C

With dimethylboron bromide; tetrabutyl ammonium fluoride; In tetrahydrofuran; dichloromethane;
DOI:10.1021/ja00249a068