C₂₇H₄₆O₆Si

Base Information

Chemical Name:C₂₇H₄₆O₆Si
CAS No.:1209386-15-1
Molecular Formula:C₂₇H₄₆O₆Si
Molecular Weight:494.744
Hs Code.:

C<sub>27</sub>H<sub>46</sub>O<sub>6</sub>Si

Synonyms:C₂₇H₄₆O₆Si

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Chemical Property of C₂₇H₄₆O₆Si

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Technology Process of C₂₇H₄₆O₆Si

There total 13 articles about C₂₇H₄₆O₆Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 1209386-14-0
C₃₅H₅₄O₇Si

: 1209386-15-1
C₂₇H₄₆O₆Si

Guidance literature:: With 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; at 0 ℃; for 0.766667h; pH=7; Inert atmosphere;
DOI:10.1021/jo400260m

Reference yield:

: C₃₄H₅₂O₇Si

: 1209386-15-1
C₂₇H₄₆O₆Si

Guidance literature:: Multi-step reaction with 2 steps

1: diethyl ether / 0 °C / Inert atmosphere

2: 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane / 0.77 h / 0 °C / pH 7 / Inert atmosphere

With 2,3-dicyano-5,6-dichloro-p-benzoquinone; In diethyl ether; dichloromethane;
DOI:10.1021/jo400260m

Reference yield:

: C₁₉H₂₈O₄

: 1209386-15-1
C₂₇H₄₆O₆Si

Guidance literature:: Multi-step reaction with 12 steps

1: trifluorormethanesulfonic acid / dichloromethane; cyclohexane / 0.5 h / 20 °C / Inert atmosphere

2: diisobutylaluminium hydride / dichloromethane; hexane / 0.08 h / -78 °C / Inert atmosphere

3: L-(+)-diisopropyl tartrate; titanium(IV) isopropylate; tert.-butylhydroperoxide / dichloromethane; decane / -20 °C / Inert atmosphere; Molecular sieve

4: dimethyl sulfoxide; sulfur trioxide pyridine complex; triethylamine / dichloromethane / 1.5 h / 0 °C / Inert atmosphere

5: dichloromethane / 0.02 h / 0 °C / Inert atmosphere

6: tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; tributylphosphine; formic acid; triethylamine / 1,4-dioxane / 9.5 h / 20 °C / Inert atmosphere

7: 2,6-dimethylpyridine / dichloromethane / 0.33 h / 0 °C / Inert atmosphere

8: diisobutylaluminium hydride / dichloromethane; hexane / 0.12 h / -78 °C / Inert atmosphere

9: D-(-)-diisopropyl tartrate; titanium(IV) isopropylate; tert.-butylhydroperoxide / dichloromethane; decane / 4 h / -20 °C / Inert atmosphere; Molecular sieve

10: 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; sodium hypochlorite; sodium chlorite / acetonitrile / 1.5 h / pH 7 / Inert atmosphere

11: diethyl ether / 0 °C / Inert atmosphere

12: 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane / 0.77 h / 0 °C / pH 7 / Inert atmosphere

With 2,6-dimethylpyridine; titanium(IV) isopropylate; tert.-butylhydroperoxide; tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; sodium hypochlorite; sodium chlorite; formic acid; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; L-(+)-diisopropyl tartrate; tributylphosphine; trifluorormethanesulfonic acid; sulfur trioxide pyridine complex; diisobutylaluminium hydride; D-(-)-diisopropyl tartrate; dimethyl sulfoxide; triethylamine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In 1,4-dioxane; diethyl ether; decane; hexane; dichloromethane; cyclohexane; acetonitrile; 3: |Sharpless Asymmetric Epoxidation / 4: |Parikh-Doering Oxidation / 5: |Horner-Wadsworth-Emmons Olefination / 9: |Sharpless Asymmetric Epoxidation;
DOI:10.1021/jo400260m