[bis(2-pyridylmethyl)bis(2-pyridyl)methylamine*Fe^II(CH₃CN)]²⁺

Base Information

• Chemical Name: [bis(2-pyridylmethyl)bis(2-pyridyl)methylamine*Fe^II(CH₃CN)]²⁺
• CAS No.: 167695-88-7
• Molecular Formula: C₂₅H₂₄FeN₆
• Molecular Weight: 464.353
• Mol file: 167695-88-7.mol

Synonyms:[bis(2-pyridylmethyl)bis(2-pyridyl)methylamine*Fe^II(CH₃CN)]²⁺

Chemical Property of [bis(2-pyridylmethyl)bis(2-pyridyl)methylamine*Fe^II(CH₃CN)]²⁺

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [bis(2-pyridylmethyl)bis(2-pyridyl)methylamine*Fe^II(CH₃CN)]²⁺

There total 3 articles about [bis(2-pyridylmethyl)bis(2-pyridyl)methylamine*Fe^II(CH₃CN)]²⁺ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

[FeO(N,N-bis(2-pyridylmethyl)-bis(2-pyridyl)methylamine)](ClO4)(1+) + triphenylmethane (519-73-3) → triphenylmethyl alcohol (76-84-6) + [bis(2-pyridylmethyl)bis(2-pyridyl)methylamine*FeII(CH3CN)]2+ (167695-88-7)

Guidance literature:

In acetonitrile; addn. of 25 equiv. of triphenylmethane to soln. of (FeO(N,N-bis(2-pyridylmethyl)-bis(2-pyridyl)methylamine))(ClO4(1+) at 25°C; monitoring by UV; Kinetics;

DOI:10.1021/ja037288n

Reference yield:

oxoiron(IV) (N,N-bis-(2-pyridylmethyl)bis(2-pyridyl)methylamine)(2+) + 1-methoxy-4-methylsulfanyl-benzene (1879-16-9) + acetonitrile (75-05-8,26809-02-9) → [bis(2-pyridylmethyl)bis(2-pyridyl)methylamine*FeII(CH3CN)]2+ (167695-88-7) + 1-methoxy-4-(methylsulfinyl)benzene (3517-99-5)

Guidance literature:

at 25 ℃; for 0.000833333h; Time; Mechanism; Kinetics; Flow reactor; Inert atmosphere;

DOI:10.1039/d0dt03083j

Reference yield:

oxoiron(IV) (N,N-bis-(2-pyridylmethyl)bis(2-pyridyl)methylamine)(2+) + p-cyanophenyl methyl sulfide (21382-98-9) + acetonitrile (75-05-8,26809-02-9) → [bis(2-pyridylmethyl)bis(2-pyridyl)methylamine*FeII(CH3CN)]2+ (167695-88-7) + 4-methanesulfinylbenzonitrile (60958-04-5,121405-10-5,97474-48-1)

Guidance literature:

at 25 ℃; for 0.000833333h; Time; Mechanism; Kinetics; Flow reactor; Inert atmosphere;

DOI:10.1039/d0dt03083j

upstream raw materials:

triphenylmethane

p-cyanophenyl methyl sulfide

acetonitrile

1-methoxy-4-methylsulfanyl-benzene