7-[(S)-4-(4,4'-dimethoxytrityloxy)-3-hydroxybutyl]-7H-7a,9-diazacyclopenta[b]phenanthrene-8,10-dione

Base Information

Chemical Name:7-[(S)-4-(4,4'-dimethoxytrityloxy)-3-hydroxybutyl]-7H-7a,9-diazacyclopenta[b]phenanthrene-8,10-dione
CAS No.:948307-66-2
Molecular Formula:C₄₀H₃₆N₂O₆
Molecular Weight:640.736
Hs Code.:

Synonyms:7-[(S)-4-(4,4'-dimethoxytrityloxy)-3-hydroxybutyl]-7H-7a,9-diazacyclopenta[b]phenanthrene-8,10-dione

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Chemical Property of 7-[(S)-4-(4,4'-dimethoxytrityloxy)-3-hydroxybutyl]-7H-7a,9-diazacyclopenta[b]phenanthrene-8,10-dione

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Technology Process of 7-[(S)-4-(4,4'-dimethoxytrityloxy)-3-hydroxybutyl]-7H-7a,9-diazacyclopenta[b]phenanthrene-8,10-dione

There total 4 articles about 7-[(S)-4-(4,4'-dimethoxytrityloxy)-3-hydroxybutyl]-7H-7a,9-diazacyclopenta[b]phenanthrene-8,10-dione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

: 948307-65-1
7-[(S)-3,4-dihydroxybutyl]-7H-7a,9-diazacyclopenta[b]phenanthrene-8,10-dione

: 40615-36-9
4,4'-dimethoxytrityl chloride

: 948307-66-2
7-[(S)-4-(4,4'-dimethoxytrityloxy)-3-hydroxybutyl]-7H-7a,9-diazacyclopenta[b]phenanthrene-8,10-dione

Guidance literature:: With triethylamine; In dichloromethane; at 20 ℃; for 48h;
DOI:10.1080/15257770600918524

Reference yield:

: 948307-64-0
7-[(S)-4-(p-biphenylcarbonyloxy)-3-hydroxybutyl]-7H-7a,9-diazacyclopenta[b]phenanthrene-8,10-dione

: 948307-66-2
7-[(S)-4-(4,4'-dimethoxytrityloxy)-3-hydroxybutyl]-7H-7a,9-diazacyclopenta[b]phenanthrene-8,10-dione

Guidance literature:: Multi-step reaction with 2 steps

1: 44 percent / ammonia / methanol / 72 h / 20 °C

2: 67 percent / triethylamine / CH₂Cl₂ / 48 h / 20 °C

With ammonia; triethylamine; In methanol; dichloromethane;
DOI:10.1080/15257770600918524

Reference yield:

: 140894-71-9
(Z)-5-(naphthalene-1-ylmethylidene)imidazolidine-2,4-dione

: 948307-66-2
7-[(S)-4-(4,4'-dimethoxytrityloxy)-3-hydroxybutyl]-7H-7a,9-diazacyclopenta[b]phenanthrene-8,10-dione

Guidance literature:: Multi-step reaction with 4 steps

1: ammonium sulfate / Heating

2: 22 percent / trimethylsilyl trifluoromethanesulfonate / acetonitrile / -30 - 5 °C

3: 44 percent / ammonia / methanol / 72 h / 20 °C

4: 67 percent / triethylamine / CH₂Cl₂ / 48 h / 20 °C

With ammonium sulfate; trimethylsilyl trifluoromethanesulfonate; ammonia; triethylamine; In methanol; dichloromethane; acetonitrile;
DOI:10.1080/15257770600918524