(4-methoxyphenyl)methyl 4,6-dideoxy-4-<<2,4,6-trideoxy-3-O-<(1,1-dimethylethyl)dimethylsilyl>-4-(methylthio-β-D-ribo-hexopyranosyl)oxy><2-(trimethylsilyl)ethoxycarbonyl>amino>-2-O-(4-amino-2,4-dideoxy-3-O-methyl-α-L-threo-pentopyranosyl)-3-O-...

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Chemical Name:(4-methoxyphenyl)methyl 4,6-dideoxy-4-<<2,4,6-trideoxy-3-O-<(1,1-dimethylethyl)dimethylsilyl>-4-(methylthio-β-D-ribo-hexopyranosyl)oxy><2-(trimethylsilyl)ethoxycarbonyl>amino>-2-O-(4-amino-2,4-dideoxy-3-O-methyl-α-L-threo-pentopyranosyl)-3-O-...
CAS No.:134286-74-1
Molecular Formula:C₄₇H₇₈N₂O₁₃SSi₂
Molecular Weight:967.379
Hs Code.:

(4-methoxyphenyl)methyl 4,6-dideoxy-4-<<2,4,6-trideoxy-3-O-<(1,1-dimethylethyl)dimethylsilyl>-4-(methylthio-β-D-ribo-hexopyranosyl)oxy><2-(trimethylsilyl)ethoxycarbonyl>amino>-2-O-(4-amino-2,4-dideoxy-3-O-methyl-α-L-threo-pentopyranosyl)-3-O-...

Synonyms:(4-methoxyphenyl)methyl 4,6-dideoxy-4-<<2,4,6-trideoxy-3-O-<(1,1-dimethylethyl)dimethylsilyl>-4-(methylthio-β-D-ribo-hexopyranosyl)oxy><2-(trimethylsilyl)ethoxycarbonyl>amino>-2-O-(4-amino-2,4-dideoxy-3-O-methyl-α-L-threo-pentopyranosyl)-3-O-...

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Chemical Property of (4-methoxyphenyl)methyl 4,6-dideoxy-4-<<2,4,6-trideoxy-3-O-<(1,1-dimethylethyl)dimethylsilyl>-4-(methylthio-β-D-ribo-hexopyranosyl)oxy><2-(trimethylsilyl)ethoxycarbonyl>amino>-2-O-(4-amino-2,4-dideoxy-3-O-methyl-α-L-threo-pentopyranosyl)-3-O-...

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Technology Process of (4-methoxyphenyl)methyl 4,6-dideoxy-4-<<2,4,6-trideoxy-3-O-<(1,1-dimethylethyl)dimethylsilyl>-4-(methylthio-β-D-ribo-hexopyranosyl)oxy><2-(trimethylsilyl)ethoxycarbonyl>amino>-2-O-(4-amino-2,4-dideoxy-3-O-methyl-α-L-threo-pentopyranosyl)-3-O-...

There total 31 articles about (4-methoxyphenyl)methyl 4,6-dideoxy-4-<<2,4,6-trideoxy-3-O-<(1,1-dimethylethyl)dimethylsilyl>-4-(methylthio-β-D-ribo-hexopyranosyl)oxy><2-(trimethylsilyl)ethoxycarbonyl>amino>-2-O-(4-amino-2,4-dideoxy-3-O-methyl-α-L-threo-pentopyranosyl)-3-O-... which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 69739-34-0
t-butyldimethylsiyl triflate

: 134286-74-1
(4-methoxyphenyl)methyl 4,6-dideoxy-4-<<2,4,6-trideoxy-3-O-<(1,1-dimethylethyl)dimethylsilyl>-4-(methylthio-β-D-ribo-hexopyranosyl)oxy><2-(trimethylsilyl)ethoxycarbonyl>amino>-2-O-(4-amino-2,4-dideoxy-3-O-methyl-α-L-threo-pentopyranosyl)-3-O-...

Guidance literature:: Multi-step reaction with 6 steps

1: pyridine / CH₂Cl₂

2: Ph₃P-HBr / CH₂Cl₂

3: EtSH, K₂CO₃ / methanol

4: 87 percent / DBU / benzene

5: NaH / dimethylformamide

6: N₂H₄ / ethanol

With pyridine; triphenylphosphine hydrobromide; sodium hydride; potassium carbonate; 1,8-diazabicyclo[5.4.0]undec-7-ene; ethanethiol; hydrazine; In methanol; ethanol; dichloromethane; N,N-dimethyl-formamide; benzene;
DOI:10.1021/jo951560x

Reference yield:

: 125848-19-3,286410-13-7
phenyl-2,4-di-O-acetyl-2,3-dideoxy-1-thio-α-D-threo-hex-2-eno-pyranoside

: 134286-74-1
(4-methoxyphenyl)methyl 4,6-dideoxy-4-<<2,4,6-trideoxy-3-O-<(1,1-dimethylethyl)dimethylsilyl>-4-(methylthio-β-D-ribo-hexopyranosyl)oxy><2-(trimethylsilyl)ethoxycarbonyl>amino>-2-O-(4-amino-2,4-dideoxy-3-O-methyl-α-L-threo-pentopyranosyl)-3-O-...

Guidance literature:: Multi-step reaction with 12 steps

1: NaOMe / methanol

2: 86 percent / TBAB / CH₂Cl₂

3: 91 percent / LAH / tetrahydrofuran

4: 1.) MsCl, Et₃N / 2.) DMF

5: 1.) LAH / 1.) THF

6: 1.) m-CBA, 2.) Et₂NH / 1.) CH₂Cl₂, 2.) THF

7: pyridine / CH₂Cl₂

8: Ph₃P-HBr / CH₂Cl₂

9: EtSH, K₂CO₃ / methanol

10: 87 percent / DBU / benzene

11: NaH / dimethylformamide

12: N₂H₄ / ethanol

With pyridine; lithium aluminium tetrahydride; m-formylphenyl benzoic acid; tetrabutylammomium bromide; sodium methylate; triphenylphosphine hydrobromide; sodium hydride; potassium carbonate; methanesulfonyl chloride; 1,8-diazabicyclo[5.4.0]undec-7-ene; diethylamine; triethylamine; ethanethiol; hydrazine; In tetrahydrofuran; methanol; ethanol; dichloromethane; N,N-dimethyl-formamide; benzene;
DOI:10.1021/jo951560x

Reference yield:

: 135726-16-8
phenyl 2,3,6-trideoxy-1-thio-α-D-threo-hex-2-enopyranoside

: 134286-74-1
(4-methoxyphenyl)methyl 4,6-dideoxy-4-<<2,4,6-trideoxy-3-O-<(1,1-dimethylethyl)dimethylsilyl>-4-(methylthio-β-D-ribo-hexopyranosyl)oxy><2-(trimethylsilyl)ethoxycarbonyl>amino>-2-O-(4-amino-2,4-dideoxy-3-O-methyl-α-L-threo-pentopyranosyl)-3-O-...

Guidance literature:: Multi-step reaction with 9 steps

1: 1.) MsCl, Et₃N / 2.) DMF

2: 1.) LAH / 1.) THF

3: 1.) m-CBA, 2.) Et₂NH / 1.) CH₂Cl₂, 2.) THF

4: pyridine / CH₂Cl₂

5: Ph₃P-HBr / CH₂Cl₂

6: EtSH, K₂CO₃ / methanol

7: 87 percent / DBU / benzene

8: NaH / dimethylformamide

9: N₂H₄ / ethanol

With pyridine; lithium aluminium tetrahydride; m-formylphenyl benzoic acid; triphenylphosphine hydrobromide; sodium hydride; potassium carbonate; methanesulfonyl chloride; 1,8-diazabicyclo[5.4.0]undec-7-ene; diethylamine; triethylamine; ethanethiol; hydrazine; In methanol; ethanol; dichloromethane; N,N-dimethyl-formamide; benzene;
DOI:10.1021/jo951560x