toluene-4-thiosulfonic acid S-[2-tert-butyl-4-(tert-butyl-dimethyl-silanyloxy)-5-methyl-phenyl] ester

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Chemical Name:toluene-4-thiosulfonic acid S-[2-tert-butyl-4-(tert-butyl-dimethyl-silanyloxy)-5-methyl-phenyl] ester
CAS No.:207737-10-8
Molecular Formula:C₂₄H₃₆O₃S₂Si
Molecular Weight:464.766
Hs Code.:

Synonyms:toluene-4-thiosulfonic acid S-[2-tert-butyl-4-(tert-butyl-dimethyl-silanyloxy)-5-methyl-phenyl] ester

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Chemical Property of toluene-4-thiosulfonic acid S-[2-tert-butyl-4-(tert-butyl-dimethyl-silanyloxy)-5-methyl-phenyl] ester

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Technology Process of toluene-4-thiosulfonic acid S-[2-tert-butyl-4-(tert-butyl-dimethyl-silanyloxy)-5-methyl-phenyl] ester

There total 7 articles about toluene-4-thiosulfonic acid S-[2-tert-butyl-4-(tert-butyl-dimethyl-silanyloxy)-5-methyl-phenyl] ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 98-51-1
4-tert-butyltoluene

: 207737-10-8
toluene-4-thiosulfonic acid S-[2-tert-butyl-4-(tert-butyl-dimethyl-silanyloxy)-5-methyl-phenyl] ester

Guidance literature:: Multi-step reaction with 7 steps

1: HNO₃, H₂SO₄ / 18.5 h / 20 - 60 °C

2: H₂ / Pd/C / 2585.74 Torr / Ambient temperature

3: 94 percent / NaNO₂, aq. H₂SO₄ / 70 °C

4: 71 percent / NaBr, Br₂ / methanol / 0 - 20 °C

5: 98 percent / imidazole / dimethylformamide / 24 h

6: DTT, K₂HPO₄ buffer / ethanol / 16 h / 80 °C

7: triethylamine / CCl₄ / 16 h / 0 °C

With 1H-imidazole; DL-dithiothreitol; K₂HPO₄ buffer; sulfuric acid; hydrogen; bromine; nitric acid; triethylamine; sodium bromide; sodium nitrite; palladium on activated charcoal; In methanol; tetrachloromethane; ethanol; N,N-dimethyl-formamide;
DOI:10.1016/S0960-894X(99)00360-1

Reference yield:

: 62559-08-4
4-tert-butyl-2-nitrotoluene

: 207737-10-8
toluene-4-thiosulfonic acid S-[2-tert-butyl-4-(tert-butyl-dimethyl-silanyloxy)-5-methyl-phenyl] ester

Guidance literature:: Multi-step reaction with 6 steps

1: H₂ / Pd/C / 2585.74 Torr / Ambient temperature

2: 94 percent / NaNO₂, aq. H₂SO₄ / 70 °C

3: 71 percent / NaBr, Br₂ / methanol / 0 - 20 °C

4: 98 percent / imidazole / dimethylformamide / 24 h

5: DTT, K₂HPO₄ buffer / ethanol / 16 h / 80 °C

6: triethylamine / CCl₄ / 16 h / 0 °C

With 1H-imidazole; DL-dithiothreitol; K₂HPO₄ buffer; sulfuric acid; hydrogen; bromine; triethylamine; sodium bromide; sodium nitrite; palladium on activated charcoal; In methanol; tetrachloromethane; ethanol; N,N-dimethyl-formamide;
DOI:10.1016/S0960-894X(99)00360-1