(3E,5E,7E,9E,11E,13E,15E)-3,7,12,16-tetramethyl-18-[(4R)-2,6,6-trimethyl-4-triethylsilyloxycyclohex-1-en-1-yl]octadeca-3,5,7,9,11,13,15-heptaen-17-yn-2-one

Base Information

Chemical Name:(3E,5E,7E,9E,11E,13E,15E)-3,7,12,16-tetramethyl-18-[(4R)-2,6,6-trimethyl-4-triethylsilyloxycyclohex-1-en-1-yl]octadeca-3,5,7,9,11,13,15-heptaen-17-yn-2-one
CAS No.:1376185-93-1
Molecular Formula:C₃₇H₅₄O₂Si
Molecular Weight:558.92
Hs Code.:

(3E,5E,7E,9E,11E,13E,15E)-3,7,12,16-tetramethyl-18-[(4R)-2,6,6-trimethyl-4-triethylsilyloxycyclohex-1-en-1-yl]octadeca-3,5,7,9,11,13,15-heptaen-17-yn-2-one

Synonyms:(3E,5E,7E,9E,11E,13E,15E)-3,7,12,16-tetramethyl-18-[(4R)-2,6,6-trimethyl-4-triethylsilyloxycyclohex-1-en-1-yl]octadeca-3,5,7,9,11,13,15-heptaen-17-yn-2-one

Suppliers and Price of (3E,5E,7E,9E,11E,13E,15E)-3,7,12,16-tetramethyl-18-[(4R)-2,6,6-trimethyl-4-triethylsilyloxycyclohex-1-en-1-yl]octadeca-3,5,7,9,11,13,15-heptaen-17-yn-2-one

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (3E,5E,7E,9E,11E,13E,15E)-3,7,12,16-tetramethyl-18-[(4R)-2,6,6-trimethyl-4-triethylsilyloxycyclohex-1-en-1-yl]octadeca-3,5,7,9,11,13,15-heptaen-17-yn-2-one

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (3E,5E,7E,9E,11E,13E,15E)-3,7,12,16-tetramethyl-18-[(4R)-2,6,6-trimethyl-4-triethylsilyloxycyclohex-1-en-1-yl]octadeca-3,5,7,9,11,13,15-heptaen-17-yn-2-one

There total 19 articles about (3E,5E,7E,9E,11E,13E,15E)-3,7,12,16-tetramethyl-18-[(4R)-2,6,6-trimethyl-4-triethylsilyloxycyclohex-1-en-1-yl]octadeca-3,5,7,9,11,13,15-heptaen-17-yn-2-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: C₃₃H₆₂OPSi⁽¹⁺⁾*Cl^(1-)

: 160456-53-1
(2E,4E,6E,8E,10E)-2,7,11-trimethyl-12-oxotrideca-2,4,6,8,10-pentaenal

: 1376185-93-1
(3E,5E,7E,9E,11E,13E,15E)-3,7,12,16-tetramethyl-18-[(4R)-2,6,6-trimethyl-4-triethylsilyloxycyclohex-1-en-1-yl]octadeca-3,5,7,9,11,13,15-heptaen-17-yn-2-one

Guidance literature:: With sodium methylate; In dichloromethane; at 0 ℃; for 0.25h; Inert atmosphere;
DOI:10.1039/c2ob25321f

Reference yield:

: 1376185-82-8
(2E,4E,6E,8E,10E)-12-tert-butyldimethylsilyloxy-2,7,11-trimethyltrideca-2,4,6,8,10-pentaenal

: 1376185-93-1
(3E,5E,7E,9E,11E,13E,15E)-3,7,12,16-tetramethyl-18-[(4R)-2,6,6-trimethyl-4-triethylsilyloxycyclohex-1-en-1-yl]octadeca-3,5,7,9,11,13,15-heptaen-17-yn-2-one

Guidance literature:: Multi-step reaction with 3 steps

1: tetrabutyl ammonium fluoride / tetrahydrofuran / 1.5 h / 40 °C / Inert atmosphere

2: 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione / dimethyl sulfoxide / 0.25 h / 20 °C / Inert atmosphere

3: sodium methylate / dichloromethane / 0.25 h / 0 °C / Inert atmosphere

With tetrabutyl ammonium fluoride; sodium methylate; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In tetrahydrofuran; dichloromethane; dimethyl sulfoxide; 3: Wittig condensation;
DOI:10.1039/c2ob25321f

Reference yield:

: 1376185-66-8
(2E)-3-methyl-5-[(4R)-2,6,6-trimethyl-4-triethylsilyloxycyclo-hex-1-en-1-yl]pent-2-en-4-yn-1-1ol

: 1376185-93-1
(3E,5E,7E,9E,11E,13E,15E)-3,7,12,16-tetramethyl-18-[(4R)-2,6,6-trimethyl-4-triethylsilyloxycyclohex-1-en-1-yl]octadeca-3,5,7,9,11,13,15-heptaen-17-yn-2-one

Guidance literature:: Multi-step reaction with 3 steps

1.1: 2,4,6-trimethyl-pyridine; lithium chloride / N,N-dimethyl-formamide / 0.17 h / -10 °C / Inert atmosphere

1.2: 1.5 h / -10 - 0 °C

2.1: triethylamine / dichloromethane / 1.5 h / 20 °C / Inert atmosphere

3.1: sodium methylate / dichloromethane / 0.25 h / 0 °C / Inert atmosphere

With 2,4,6-trimethyl-pyridine; sodium methylate; triethylamine; lithium chloride; In dichloromethane; N,N-dimethyl-formamide; 2.1: Wittig reaction / 3.1: Wittig condensation;
DOI:10.1039/c2ob25321f