(o-isocyanobenzyl)pentacarbonylmanganese

Base Information

Chemical Name:(o-isocyanobenzyl)pentacarbonylmanganese
CAS No.:91949-16-5
Molecular Formula:C₁₃H₆MnNO₅
Molecular Weight:311.132
Hs Code.:

Synonyms:(o-isocyanobenzyl)pentacarbonylmanganese

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Chemical Property of (o-isocyanobenzyl)pentacarbonylmanganese

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Technology Process of (o-isocyanobenzyl)pentacarbonylmanganese

There total 1 articles about (o-isocyanobenzyl)pentacarbonylmanganese which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.5%

: 10170-69-1
dimanganese decacarbonyl

: 88644-60-4
o-(iodomethyl)phenyl isocyanide

: 91949-16-5
(o-isocyanobenzyl)pentacarbonylmanganese

Guidance literature:: With sodium amalgam; In tetrahydrofuran; Na/Hg was treated with a stirred soln. of complex in THF, the mixt. wasstirred at room temp. for 3 h, filtered, colled to -78°C, solid ligand was added, the mixt. was allowed to warm to -20°C for ca. 3 h (inert atm.);; evapd. at -20°C., dissolved in toluene, chromd. on Florisil column, reduced in vol., pentane was added, stored at -78°C for 3 days; elem. anal.;;

Reference yield:

: 91949-16-5
(o-isocyanobenzyl)pentacarbonylmanganese

: 10170-69-1
dimanganese decacarbonyl

: 91949-17-6
[Mn(CO)4(o-CH₂C₆H₄NC)]2

Guidance literature:: In tetrahydrofuran; A soln. of complex in THF was refluxed under N2 for 3 days;; evapd., to dryness, dissolved in benzene, chromd. in a Florisil column with hexane-CH2Cl2;;

Reference yield:

: [Pt(μ-Cl)Cl(triphenylphosphine)]2

: 91949-16-5
(o-isocyanobenzyl)pentacarbonylmanganese

: 91949-10-9
cis-PtCl₂(PPh₃)Mn(CO)5(o-CH₂C₆H₄NC)

Guidance literature:: In benzene; The mixt. of reagents in C6H6 at room temp. was stirred for 1 h (inert atm.);; concd., Et2O was added, filtered, crystd. from CH2Cl2-Et2O; elem. anal.;;