[bis(triphenylphosphine)nitrogen(1+)]][Os3(η1-C(O)(Me))(CO)11]

Base Information

• Chemical Name: [bis(triphenylphosphine)nitrogen(1+)]][Os3(η1-C(O)(Me))(CO)11]
• CAS No.: 91383-69-6
• Molecular Formula: C₁₃H₃O₁₂Os₃*C₃₆H₃₀NP₂
• Molecular Weight: 1460.35
• Mol file: 91383-69-6.mol

Synonyms:[bis(triphenylphosphine)nitrogen(1+)]][Os3(η1-C(O)(Me))(CO)11]

Chemical Property of [bis(triphenylphosphine)nitrogen(1+)]][Os3(η1-C(O)(Me))(CO)11]

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of [bis(triphenylphosphine)nitrogen(1+)]][Os3(η1-C(O)(Me))(CO)11]

There total 1 articles about [bis(triphenylphosphine)nitrogen(1+)]][Os3(η1-C(O)(Me))(CO)11] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[Li][Os3(η1-C(O)(Me))(CO)11] (80800-44-8) + bis(triphenylphosphine)iminium chloride (21050-13-5) → [bis(triphenylphosphine)nitrogen(1+)]][Os3(η1-C(O)(Me))(CO)11] (91383-69-6)

Guidance literature:

In tetrahydrofuran; methanol; byproducts: LiCl; under N2, to soln. of Os complex in THF (PPN)Cl in MeOH added; not isolated; IR anal.;

DOI:10.1021/ja00332a029

Reference yield: 87.0%

[bis(triphenylphosphine)nitrogen(1+)]][Os3(η1-C(O)(Me))(CO)11] (91383-69-6) → dodecacarbonyl triosmium (15696-40-9) + [bis(triphenylphosphine)nitrogen(1+)]][Os3(1,2-μ-O=C(Me))(CO)10] (91327-52-5)

Guidance literature:

In tetrahydrofuran; chloroform; under N2, soln. of educt in THF stirred at 25°C for 24 h, concd., filtered, evapd. in vac., CHCl3 added, the all procedure repeated for several times;

DOI:10.1021/ja00332a029

upstream raw materials:

[Li][Os3(η1-C(O)(Me))(CO)11]

bis(triphenylphosphine)iminium chloride

Downstream raw materials:

dodecacarbonyl triosmium

[bis(triphenylphosphine)nitrogen(1+)]][Os3(1,2-μ-O=C(Me))(CO)10]