(1S,2S,4S)-7-<(benzyloxy)methoxy>-2,9-dihydroxy-p-methane-7-carbonitrile

Base Information

Chemical Name:(1S,2S,4S)-7-<(benzyloxy)methoxy>-2,9-dihydroxy-p-methane-7-carbonitrile
CAS No.:88670-93-3
Molecular Formula:C₁₉H₂₇NO₄
Molecular Weight:333.428
Hs Code.:

Synonyms:(1S,2S,4S)-7-<(benzyloxy)methoxy>-2,9-dihydroxy-p-methane-7-carbonitrile

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Chemical Property of (1S,2S,4S)-7-<(benzyloxy)methoxy>-2,9-dihydroxy-p-methane-7-carbonitrile

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Technology Process of (1S,2S,4S)-7-<(benzyloxy)methoxy>-2,9-dihydroxy-p-methane-7-carbonitrile

There total 4 articles about (1S,2S,4S)-7-<(benzyloxy)methoxy>-2,9-dihydroxy-p-methane-7-carbonitrile which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 18031-40-8
(S)-(-)-perillaldehyde

: 88670-93-3
(1S,2S,4S)-7-<(benzyloxy)methoxy>-2,9-dihydroxy-p-methane-7-carbonitrile

Guidance literature:: Multi-step reaction with 3 steps

1: 95 percent / HOAc / diethyl ether / 25 °C

2: 51 percent / pyridine / 60 °C

3: 1.) thexylborane, 2.) H₂O, NaOAc / 1) THF, -40 deg C

With pyridine; thexylborane; water; sodium acetate; acetic acid; In diethyl ether;
DOI:10.1021/ja00380a035

Reference yield:

: 82167-73-5
(4S)-7-<(benzyloxy)methoxy>-p-mentha-1,8-diene-7-carbonitrile

: 88670-93-3
(1S,2S,4S)-7-<(benzyloxy)methoxy>-2,9-dihydroxy-p-methane-7-carbonitrile

Guidance literature:: With thexylborane; dihydrogen peroxide; sodium acetate; Yield given. Multistep reaction; 1.a.) -40 deg C 1.b.) 3 h, 23 deg C 2.) 1 h, 50 deg C;
DOI:10.1021/jo00179a018

Reference yield:

: 3587-60-8
Benzyloxymethyl chloride

: 88670-93-3
(1S,2S,4S)-7-<(benzyloxy)methoxy>-2,9-dihydroxy-p-methane-7-carbonitrile

Guidance literature:: Multi-step reaction with 2 steps

1: 51 percent / pyridine / 60 °C

2: 1.) thexylborane, 2.) H₂O, NaOAc / 1) THF, -40 deg C

With pyridine; thexylborane; water; sodium acetate;
DOI:10.1021/ja00380a035