2-Methyl-4-((E)-2-phenyl-propenyl)-tricyclo[11.2.2.2^5,8]nonadeca-1⁽¹⁶⁾,5,7,13⁽¹⁷⁾,14,18-hexaene

Base Information

• Chemical Name: 2-Methyl-4-((E)-2-phenyl-propenyl)-tricyclo[11.2.2.2^5,8]nonadeca-1⁽¹⁶⁾,5,7,13⁽¹⁷⁾,14,18-hexaene
• CAS No.: 101472-21-3
• Molecular Formula: C₂₉H₃₂
• Molecular Weight: 380.573

Synonyms:2-Methyl-4-((E)-2-phenyl-propenyl)-tricyclo[11.2.2.2^5,8]nonadeca-1⁽¹⁶⁾,5,7,13⁽¹⁷⁾,14,18-hexaene

Chemical Property of 2-Methyl-4-((E)-2-phenyl-propenyl)-tricyclo[11.2.2.2^5,8]nonadeca-1⁽¹⁶⁾,5,7,13⁽¹⁷⁾,14,18-hexaene

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Technology Process of 2-Methyl-4-((E)-2-phenyl-propenyl)-tricyclo[11.2.2.2^5,8]nonadeca-1⁽¹⁶⁾,5,7,13⁽¹⁷⁾,14,18-hexaene

There total 1 articles about 2-Methyl-4-((E)-2-phenyl-propenyl)-tricyclo[11.2.2.2^5,8]nonadeca-1⁽¹⁶⁾,5,7,13⁽¹⁷⁾,14,18-hexaene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 25.0%

1,4-bis(p-vinylphenyl)-butane (41996-99-0) + isopropenylbenzene (98-83-9,6144-04-3,25014-31-7,42612-14-6) → 2-Methyl-4-((E)-2-phenyl-propenyl)-tricyclo[11.2.2.25,8]nonadeca-1(16),5,7,13(17),14,18-hexaene (101472-21-3)

Guidance literature:

With trifluorormethanesulfonic acid; In hexane; at 50 ℃; for 0.333333h;

DOI:10.1021/jo00360a034

Reference yield:

2-Methyl-4-((E)-2-phenyl-propenyl)-tricyclo[11.2.2.25,8]nonadeca-1(16),5,7,13(17),14,18-hexaene (101472-21-3) → cis-1-methyl-3-((tosyloxy)methyl)<3.4>paracyclophane (101472-37-1)

Guidance literature:

Multi-step reaction with 3 steps

2: 100 percent / LiAlH₄ / diethyl ether

3: 100 percent / pyridine / 0 - 25 °C

With pyridine; lithium aluminium tetrahydride; In diethyl ether;

DOI:10.1021/jo00360a034

Reference yield:

2-Methyl-4-((E)-2-phenyl-propenyl)-tricyclo[11.2.2.25,8]nonadeca-1(16),5,7,13(17),14,18-hexaene (101472-21-3) → Toluene-4-sulfonic acid 1-((2R,4S)-4-methyl-tricyclo[11.2.2.25,8]nonadeca-1(16),5,7,13(17),14,18-hexaen-2-yl)-ethyl ester (101472-41-7)

Guidance literature:

Multi-step reaction with 3 steps

2: 100 percent / diethyl ether

3: 100 percent / pyridine / 0 - 25 °C

With pyridine; In diethyl ether;

DOI:10.1021/jo00360a034

upstream raw materials:

1,4-bis(p-vinylphenyl)-butane

isopropenylbenzene

Downstream raw materials:

cis-1-methyl-3-((tosyloxy)methyl)<3.4>paracyclophane

Toluene-4-sulfonic acid 1-((2R,4S)-4-methyl-tricyclo[11.2.2.2^5,8]nonadeca-1⁽¹⁶⁾,5,7,13⁽¹⁷⁾,14,18-hexaen-2-yl)-ethyl ester

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