5-(benzyloxymethyl)cyclopentadiene

Base Information

• Chemical Name: 5-(benzyloxymethyl)cyclopentadiene
• CAS No.: 39939-07-6
• Molecular Formula: C₁₃H₁₄O
• Molecular Weight: 186.254
• Mol file: 39939-07-6.mol

Synonyms:5-(benzyloxymethyl)cyclopentadiene

Chemical Property of 5-(benzyloxymethyl)cyclopentadiene

Chemical Property:

• Boiling Point: 271.9±9.0 °C(Predicted)
• Density: 1.035±0.06 g/cm3(Predicted)

Purity/Quality:

95+% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 5-(benzyloxymethyl)cyclopentadiene

There total 9 articles about 5-(benzyloxymethyl)cyclopentadiene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Benzyloxymethyl chloride (3587-60-8) + cyclopentadienylthallium (34822-90-7) → 5-(benzyloxymethyl)cyclopentadiene (39939-07-6)

Guidance literature:

In diethyl ether; at -20 ℃; for 18h;

DOI:10.1021/jo00358a023

Reference yield:

Benzyloxymethyl chloride (3587-60-8) + sodium cyclopentadienide → 5-(benzyloxymethyl)cyclopentadiene (39939-07-6)

Guidance literature:

In N,N-dimethyl-formamide; at -40 ℃; for 0.25h;

DOI:10.1002/jlcr.1664

Reference yield:

Benzyloxymethyl chloride (3587-60-8) + cyclopentadienylthallium(I) → 5-(benzyloxymethyl)cyclopentadiene (39939-07-6)

Guidance literature:

In diethyl ether; at -20 ℃;

upstream raw materials:

Benzyloxymethyl chloride

cyclopentadienylthallium

cyclopenta-1,3-diene

benzyl alcohol

Downstream raw materials:

4-Benzyloxymethyl-5-chlor-5-cyano-2-norbornen

(-)-(1R,2S,4S,7R)-7-benzyloxymethyl-2-formylbicyclo[2.2.1]hept-5-en-2-yl p-methoxybenzoate

Refernces

• 1、 -. "PCSK9 INHIBITORS AND METHODS OF USE THEREOF". Page/Page column 146-147. . Retrieved 2020/07/31.
• 2、 Pujol, Adeline R.,Ratel-Ramond, Nicolas,Gourdon, André. "Cis,cis,cis,cis-1,2,3,4,5-Pentakis(hydroxymethyl)cyclopentane". . p. 9139 - 9144. Retrieved 2013/09/24.