(S,R)-(2,2'-bs(diphenylphosphanyl)biphenyl)(2,2'-bis(trifluoromethanesulfonylamido)-1,1'-binaphthyl)platinum(II)

Base Information

• Chemical Name: (S,R)-(2,2'-bs(diphenylphosphanyl)biphenyl)(2,2'-bis(trifluoromethanesulfonylamido)-1,1'-binaphthyl)platinum(II)
• CAS No.: 916073-86-4
• Molecular Formula: C₅₈H₄₀F₆N₂O₄P₂PtS₂
• Molecular Weight: 1264.12
• Mol file: 916073-86-4.mol

Synonyms:(S,R)-(2,2'-bs(diphenylphosphanyl)biphenyl)(2,2'-bis(trifluoromethanesulfonylamido)-1,1'-binaphthyl)platinum(II)

Chemical Property of (S,R)-(2,2'-bs(diphenylphosphanyl)biphenyl)(2,2'-bis(trifluoromethanesulfonylamido)-1,1'-binaphthyl)platinum(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (S,R)-(2,2'-bs(diphenylphosphanyl)biphenyl)(2,2'-bis(trifluoromethanesulfonylamido)-1,1'-binaphthyl)platinum(II)

There total 2 articles about (S,R)-(2,2'-bs(diphenylphosphanyl)biphenyl)(2,2'-bis(trifluoromethanesulfonylamido)-1,1'-binaphthyl)platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(2,2'-bis(diphenylphosphanyl)biphenyl)PtCO3 → (S,R)-(2,2'-bs(diphenylphosphanyl)biphenyl)(2,2'-bis(trifluoromethanesulfonylamido)-1,1'-binaphthyl)platinum(II) (916073-86-4)

Guidance literature:

Multi-step reaction with 2 steps

1: ⁽²⁾H₈-toluene

2: ⁽²⁾H₈-toluene

In ⁽²⁾H₈-toluene;

DOI:10.1002/anie.200502682

Reference yield:

(R)-2,2'-bis(trifluoromethanesulfonylamino)-1,1'-binaphthyl (55442-11-0,143131-81-1) + (2,2'-bis(diphenylphosphanyl)biphenyl)PtCO3 → (S,R)-(2,2'-bs(diphenylphosphanyl)biphenyl)(2,2'-bis(trifluoromethanesulfonylamido)-1,1'-binaphthyl)platinum(II) (916073-86-4) + (R)-(2,2'-bis(diphenylphosphanyl)biphenyl)PtCO3 (307928-35-4,874432-97-0)

Guidance literature:

In ⁽²⁾H₈-toluene; reaction at temp. lower than 50 °C; detd. by NMR;

DOI:10.1002/anie.200502682

Reference yield: 99.0%

hydrogenchloride (7647-01-0,15364-23-5) + (S,R)-(2,2'-bs(diphenylphosphanyl)biphenyl)(2,2'-bis(trifluoromethanesulfonylamido)-1,1'-binaphthyl)platinum(II) (916073-86-4) → (S)-(2,2'-bs(diphenylphosphanyl)biphenyl)dichloroplatinum(II) (308084-79-9,170940-43-9,372077-28-6)

Guidance literature:

In dichloromethane; byproducts: (R)-(C10H6NHSO2CF3)2; reaction with conc. HCl at room temp. for 2 h; detd. by (1)H and (31)P NMR;

DOI:10.1002/anie.200502682

upstream raw materials:

(R)-2,2'-bis(trifluoromethanesulfonylamino)-1,1'-binaphthyl

Downstream raw materials:

(S)-(2,2'-bs(diphenylphosphanyl)biphenyl)dichloroplatinum(II)