triethyl 2,2',2-((4-(trimethylsilyl)ethynyl-1,3,5-phenylene)tris(oxy))-triacetate

Base Information

Chemical Name:triethyl 2,2',2-((4-(trimethylsilyl)ethynyl-1,3,5-phenylene)tris(oxy))-triacetate
CAS No.:1425510-06-0
Molecular Formula:C₂₃H₃₂O₉Si
Molecular Weight:480.587
Hs Code.:

Synonyms:triethyl 2,2',2-((4-(trimethylsilyl)ethynyl-1,3,5-phenylene)tris(oxy))-triacetate

Suppliers and Price of triethyl 2,2',2-((4-(trimethylsilyl)ethynyl-1,3,5-phenylene)tris(oxy))-triacetate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of triethyl 2,2',2-((4-(trimethylsilyl)ethynyl-1,3,5-phenylene)tris(oxy))-triacetate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of triethyl 2,2',2-((4-(trimethylsilyl)ethynyl-1,3,5-phenylene)tris(oxy))-triacetate

There total 4 articles about triethyl 2,2',2-((4-(trimethylsilyl)ethynyl-1,3,5-phenylene)tris(oxy))-triacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 1425510-27-5
diethyl 2,2'-((4-bromo-1,3-phenylene)bis(oxy))diacetate

: 1066-54-2
trimethylsilylacetylene

: 1425510-06-0
triethyl 2,2',2-((4-(trimethylsilyl)ethynyl-1,3,5-phenylene)tris(oxy))-triacetate

Guidance literature:: With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; In diethylamine; N,N-dimethyl-formamide; at 100 ℃; for 0.5h; Inert atmosphere; Microwave irradiation;
DOI:10.3390/molecules22101807

Reference yield: 70.0%

: 1425510-05-9
triethyl 2,2',2-((4-iodo-1,3,5-phenylene)tris(oxy))triacetate

: 1066-54-2
trimethylsilylacetylene

: 1425510-06-0
triethyl 2,2',2-((4-(trimethylsilyl)ethynyl-1,3,5-phenylene)tris(oxy))-triacetate

Guidance literature:: With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; diethylamine; triphenylphosphine; In dichloromethane; N,N-dimethyl-formamide; at 100 - 120 ℃; for 0.833333h; Sealed tube; Inert atmosphere; Microwave irradiation;

Reference yield:

: 6626-15-9
4-Bromoresorcinol

: 1425510-06-0
triethyl 2,2',2-((4-(trimethylsilyl)ethynyl-1,3,5-phenylene)tris(oxy))-triacetate

Guidance literature:: Multi-step reaction with 2 steps

1: potassium carbonate / 24 h / 50 °C

2: bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide / diethylamine; N,N-dimethyl-formamide / 0.5 h / 100 °C / Inert atmosphere; Microwave irradiation

With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; potassium carbonate; In diethylamine; N,N-dimethyl-formamide; 2: |Sonogashira Cross-Coupling;
DOI:10.3390/molecules22101807