6-benzyloxy-1,2,8-trimethoxy-7-methyl-5-(2-methyl-allyl)-10,11-dihydro-5H-dibenzo[a,d]cyclohepten-5-ol

Base Information

Chemical Name:6-benzyloxy-1,2,8-trimethoxy-7-methyl-5-(2-methyl-allyl)-10,11-dihydro-5H-dibenzo[a,d]cyclohepten-5-ol
CAS No.:874771-70-7
Molecular Formula:C₃₀H₃₄O₅
Molecular Weight:474.597
Hs Code.:

6-benzyloxy-1,2,8-trimethoxy-7-methyl-5-(2-methyl-allyl)-10,11-dihydro-5<i>H</i>-dibenzo[<i>a</i>,<i>d</i>]cyclohepten-5-ol

Synonyms:6-benzyloxy-1,2,8-trimethoxy-7-methyl-5-(2-methyl-allyl)-10,11-dihydro-5H-dibenzo[a,d]cyclohepten-5-ol

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Chemical Property of 6-benzyloxy-1,2,8-trimethoxy-7-methyl-5-(2-methyl-allyl)-10,11-dihydro-5H-dibenzo[a,d]cyclohepten-5-ol

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Technology Process of 6-benzyloxy-1,2,8-trimethoxy-7-methyl-5-(2-methyl-allyl)-10,11-dihydro-5H-dibenzo[a,d]cyclohepten-5-ol

There total 6 articles about 6-benzyloxy-1,2,8-trimethoxy-7-methyl-5-(2-methyl-allyl)-10,11-dihydro-5H-dibenzo[a,d]cyclohepten-5-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 874771-65-0
6-benzyloxy-1,2,8-trimethoxy-7-methyl-10,11-dihydro-dibenzo[a,d]cyclohepten-5-one

: 5674-01-1
2-methylallylmagnesium chloride

: 874771-70-7
6-benzyloxy-1,2,8-trimethoxy-7-methyl-5-(2-methyl-allyl)-10,11-dihydro-5H-dibenzo[a,d]cyclohepten-5-ol

Guidance literature:: In tetrahydrofuran; at -20 - 20 ℃;
DOI:10.1016/j.tetlet.2005.11.016

Reference yield:

: 874771-62-7
6-[2-(2,3-dimethoxy-phenyl)-ethyl]-2,4-dimethoxy-3-methyl-benzoic acid methyl ester

: 874771-70-7
6-benzyloxy-1,2,8-trimethoxy-7-methyl-5-(2-methyl-allyl)-10,11-dihydro-5H-dibenzo[a,d]cyclohepten-5-ol

Guidance literature:: Multi-step reaction with 4 steps

1: 92 percent / PPA

2: 92 percent / BBr₃ / CH₂Cl₂ / -78 °C

3: 95 percent / K₂CO₃ / acetone / Heating

4: 75 percent / tetrahydrofuran / -20 - 20 °C

With boron tribromide; potassium carbonate; In tetrahydrofuran; dichloromethane; acetone; 1: intramolecular Friedel-Crafts acylation / 4: Grignard reaction;
DOI:10.1016/j.tetlet.2005.11.016

Reference yield:

: 874771-61-6
1,2,6,8-tetramethoxy-7-methyl-10,11-dihydro-dibenzo[a,d]cyclohepten-5-one

: 874771-70-7
6-benzyloxy-1,2,8-trimethoxy-7-methyl-5-(2-methyl-allyl)-10,11-dihydro-5H-dibenzo[a,d]cyclohepten-5-ol

Guidance literature:: Multi-step reaction with 3 steps

1: 92 percent / BBr₃ / CH₂Cl₂ / -78 °C

2: 95 percent / K₂CO₃ / acetone / Heating

3: 75 percent / tetrahydrofuran / -20 - 20 °C

With boron tribromide; potassium carbonate; In tetrahydrofuran; dichloromethane; acetone; 3: Grignard reaction;
DOI:10.1016/j.tetlet.2005.11.016