1-(4,4'-dimethoxytrityloxy)-29-[4-(1-hydroxyprop-2-en-1-yl)phenyl]methylenoxy-3,6,9,12,15,18,21,24,27-nonaoxanonacosane

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Chemical Name:1-(4,4'-dimethoxytrityloxy)-29-[4-(1-hydroxyprop-2-en-1-yl)phenyl]methylenoxy-3,6,9,12,15,18,21,24,27-nonaoxanonacosane
CAS No.:860030-82-6
Molecular Formula:C₅₁H₇₀O₁₄
Molecular Weight:907.108
Hs Code.:

Synonyms:1-(4,4'-dimethoxytrityloxy)-29-[4-(1-hydroxyprop-2-en-1-yl)phenyl]methylenoxy-3,6,9,12,15,18,21,24,27-nonaoxanonacosane

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Chemical Property of 1-(4,4'-dimethoxytrityloxy)-29-[4-(1-hydroxyprop-2-en-1-yl)phenyl]methylenoxy-3,6,9,12,15,18,21,24,27-nonaoxanonacosane

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Technology Process of 1-(4,4'-dimethoxytrityloxy)-29-[4-(1-hydroxyprop-2-en-1-yl)phenyl]methylenoxy-3,6,9,12,15,18,21,24,27-nonaoxanonacosane

There total 10 articles about 1-(4,4'-dimethoxytrityloxy)-29-[4-(1-hydroxyprop-2-en-1-yl)phenyl]methylenoxy-3,6,9,12,15,18,21,24,27-nonaoxanonacosane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 860030-81-5
1-(4,4'-dimethoxytrityloxy)-29-[4-(1-tert-butyldimethylsilyloxyprop-2-en-1-yl)phenyl]methylenoxy-3,6,9,12,15,18,21,24,27-nonaoxanonacosane

: 860030-82-6
1-(4,4'-dimethoxytrityloxy)-29-[4-(1-hydroxyprop-2-en-1-yl)phenyl]methylenoxy-3,6,9,12,15,18,21,24,27-nonaoxanonacosane

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 20 ℃; for 1h;
DOI:10.1021/ja051179m

Reference yield:

: 860030-76-8
1-(4-chloromethylphenyl)prop-2-en-1-ol

: 860030-82-6
1-(4,4'-dimethoxytrityloxy)-29-[4-(1-hydroxyprop-2-en-1-yl)phenyl]methylenoxy-3,6,9,12,15,18,21,24,27-nonaoxanonacosane

Guidance literature:: Multi-step reaction with 3 steps

1.1: 99 percent / imidazole / dimethylformamide / 1 h / 20 °C

2.1: NaH / acetonitrile / 0.08 h / 20 °C

2.2: 90 percent / NaI / acetonitrile / 1.5 h / 40 °C

3.1: 90 percent / TBAF / tetrahydrofuran / 1 h / 20 °C

With 1H-imidazole; tetrabutyl ammonium fluoride; sodium hydride; In tetrahydrofuran; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1021/ja051179m

Reference yield:

: 860030-77-9
1-tert-butyldimethylsilyloxy-1-(4-chloromethylphenyl)prop-2-en

: 860030-82-6
1-(4,4'-dimethoxytrityloxy)-29-[4-(1-hydroxyprop-2-en-1-yl)phenyl]methylenoxy-3,6,9,12,15,18,21,24,27-nonaoxanonacosane

Guidance literature:: Multi-step reaction with 2 steps

1.1: NaH / acetonitrile / 0.08 h / 20 °C

1.2: 90 percent / NaI / acetonitrile / 1.5 h / 40 °C

2.1: 90 percent / TBAF / tetrahydrofuran / 1 h / 20 °C

With tetrabutyl ammonium fluoride; sodium hydride; In tetrahydrofuran; acetonitrile;
DOI:10.1021/ja051179m