{molybdenum⁽⁰⁾tricarbonyl{bis(diphenylphosphinyl)methyl}phenylphosphine oxide}}

Base Information

• Chemical Name: {molybdenum⁽⁰⁾tricarbonyl{bis(diphenylphosphinyl)methyl}phenylphosphine oxide}}
• CAS No.: 121777-62-6
• Molecular Formula: C₃₅H₂₉MoO₆P₃
• Molecular Weight: 734.473
• Mol file: 121777-62-6.mol

Synonyms:{molybdenum⁽⁰⁾tricarbonyl{bis(diphenylphosphinyl)methyl}phenylphosphine oxide}}

Chemical Property of {molybdenum⁽⁰⁾tricarbonyl{bis(diphenylphosphinyl)methyl}phenylphosphine oxide}}

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {molybdenum⁽⁰⁾tricarbonyl{bis(diphenylphosphinyl)methyl}phenylphosphine oxide}}

There total 1 articles about {molybdenum⁽⁰⁾tricarbonyl{bis(diphenylphosphinyl)methyl}phenylphosphine oxide}} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

1,1,3,5,5-pentaphenyl-1,3,5-triphosphapentane trioxide (21851-89-8) + molybdenum hexacarbonyl (13939-06-5,199620-15-0) → fac-(bis{(diphenylphosphinyl)methyl}phenylphosphine oxide)(tricarbonyl)molybdenum(0) (121777-62-6)

Guidance literature:

In benzene; Ar atmosphere, refluxing with stirring (3 h), cooling to room temp.; filtration, washing (benzene), drying (vac. of water suction pipe); elem. anal.;

DOI:10.1016/S0277-5387(00)83824-3

Reference yield: 86.0%

{molybdenum(0)tricarbonyl{bis(diphenylphosphinyl)methyl}phenylphosphine oxide}} (121777-62-6) → {molybdenum(II)tricarbonyl{bis(diphenylphosphinyl)methyl}phenylphosphine oxide}I2} (129182-00-9)

Guidance literature:

With I₂; In tetrachloromethane; addn. of I2 in CCl4 to a suspn. of the Mo complex in CCl4 at -5°C (stirring over 4 h, under a stream of dry Ar), pptn.; filtering off, washing (CCl4), drying (vac., over P4O10); elem. anal.;

DOI:10.1016/S0277-5387(00)81301-7

upstream raw materials:

1,1,3,5,5-pentaphenyl-1,3,5-triphosphapentane trioxide

molybdenum hexacarbonyl

Downstream raw materials:

{molybdenum(II)tricarbonyl{bis(diphenylphosphinyl)methyl}phenylphosphine oxide}I₂}