2-methyl-1,1'-bis(diphenylphosphino)ferrocene

Base Information

• Chemical Name: 2-methyl-1,1'-bis(diphenylphosphino)ferrocene
• CAS No.: 407626-00-0
• Molecular Formula: C₃₅H₃₀FeP₂
• Molecular Weight: 568.418
• Mol file: 407626-00-0.mol

Synonyms:2-methyl-1,1'-bis(diphenylphosphino)ferrocene

Chemical Property of 2-methyl-1,1'-bis(diphenylphosphino)ferrocene

Chemical Property:

Purity/Quality:

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Technology Process of 2-methyl-1,1'-bis(diphenylphosphino)ferrocene

There total 1 articles about 2-methyl-1,1'-bis(diphenylphosphino)ferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

2-(hydroxymethyl)-1,1'-bis(diphenylphosphino)ferrocene (407626-16-8) → 2-methyl-1,1'-bis(diphenylphosphino)ferrocene (407626-00-0)

Guidance literature:

With LiAlH₄; AlCl₃; In 1,2-dimethoxyethane; under N2, standard Schlenk techniques; AlCl3 (1.2 equiv.) added to LiAlH4 (12 equiv.) in dry DME; stirred at room temp. for 2 h; 1 equiv. of Fe complex in dry DME added dropwise; stirred at 90°C for 15 h; water added at 0°C; org. phase sepd.; aq. phase extd. with Et2O; combined org. phases washedwith brine; dried over anhyd. Na2SO4; filtered; solvent removed from fi ltrate under reduced pressure; chromy. (alumina, petroleum ether/ethyl acetate (4/1)); elem. anal.;

DOI:10.1021/om010656g

Reference yield: 85.0%

bis(pentafluorophenyl)(1,5-cyclo-octadiene)palladium(II) (105286-78-0) + 2-methyl-1,1'-bis(diphenylphosphino)ferrocene (407626-00-0) → Pd(pentafluorophenyl)2(2-methyl-1,1'-bis(diphenylphosphino)ferrocene)

Guidance literature:

In toluene; byproducts: 1,5-cyclooctadiene; under N2, standard Schlenk techniques; Pd complex added to soln. of Fe complex (molar ratio 1:1) in toluene; stirred for 16 h at room temp.; evapd. to dryness; washed with hexane; crystd. from CH2Cl2-pentane; elem. anal.;

DOI:10.1021/om010656g

upstream raw materials:

2-(hydroxymethyl)-1,1'-bis(diphenylphosphino)ferrocene