2-[4-(3,5-di-t-butylbenzylthio)-5-(ethylthio)-1,3-dithiole-2-ylidene]-5-{2-[2-(2-iodoethoxy)ethoxy]ethyl}-[1,3]dithiolo[4,5-c]pyrrole

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Chemical Name:2-[4-(3,5-di-t-butylbenzylthio)-5-(ethylthio)-1,3-dithiole-2-ylidene]-5-{2-[2-(2-iodoethoxy)ethoxy]ethyl}-[1,3]dithiolo[4,5-c]pyrrole
CAS No.:1357295-20-5
Molecular Formula:C₃₁H₄₂INO₂S₆
Molecular Weight:779.98
Hs Code.:

Synonyms:2-[4-(3,5-di-t-butylbenzylthio)-5-(ethylthio)-1,3-dithiole-2-ylidene]-5-{2-[2-(2-iodoethoxy)ethoxy]ethyl}-[1,3]dithiolo[4,5-c]pyrrole

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Chemical Property of 2-[4-(3,5-di-t-butylbenzylthio)-5-(ethylthio)-1,3-dithiole-2-ylidene]-5-{2-[2-(2-iodoethoxy)ethoxy]ethyl}-[1,3]dithiolo[4,5-c]pyrrole

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Technology Process of 2-[4-(3,5-di-t-butylbenzylthio)-5-(ethylthio)-1,3-dithiole-2-ylidene]-5-{2-[2-(2-iodoethoxy)ethoxy]ethyl}-[1,3]dithiolo[4,5-c]pyrrole

There total 4 articles about 2-[4-(3,5-di-t-butylbenzylthio)-5-(ethylthio)-1,3-dithiole-2-ylidene]-5-{2-[2-(2-iodoethoxy)ethoxy]ethyl}-[1,3]dithiolo[4,5-c]pyrrole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 36839-55-1
1,2-bis-(2-iodoethoxy)ethane

: 1357295-19-2
2-[4-(3,5-di-t-butylbenzylthio)-5-(ethylthio)-1,3-dithiole-2-ylidene]-[1,3]dithiolo[4,5-c]pyrrole

: 1357295-20-5
2-[4-(3,5-di-t-butylbenzylthio)-5-(ethylthio)-1,3-dithiole-2-ylidene]-5-{2-[2-(2-iodoethoxy)ethoxy]ethyl}-[1,3]dithiolo[4,5-c]pyrrole

Guidance literature:: 1,2-bis-(2-iodoethoxy)ethane; 2-[4-(3,5-di-t-butylbenzylthio)-5-(ethylthio)-1,3-dithiole-2-ylidene]-[1,3]dithiolo[4,5-c]pyrrole; In N,N-dimethyl-formamide; at 20 ℃; for 0.166667h; Inert atmosphere;

With sodium hydride; In N,N-dimethyl-formamide; mineral oil; at 20 ℃; for 1h; Inert atmosphere;
DOI:10.1021/ja210861v

Reference yield:

: 62938-08-3
3,5-di-tert-butylbenzyl bromide

: 1357295-20-5
2-[4-(3,5-di-t-butylbenzylthio)-5-(ethylthio)-1,3-dithiole-2-ylidene]-5-{2-[2-(2-iodoethoxy)ethoxy]ethyl}-[1,3]dithiolo[4,5-c]pyrrole

Guidance literature:: Multi-step reaction with 3 steps

1.1: tetrahydrofuran / 0.5 h / Inert atmosphere

1.2: 24 h / 20 °C / Inert atmosphere

2.1: tetrahydrofuran; methanol / 0.33 h / Inert atmosphere

2.2: 0.5 h / 20 °C / Reflux; Inert atmosphere

3.1: N,N-dimethyl-formamide / 0.17 h / 20 °C / Inert atmosphere

3.2: 1 h / 20 °C / Inert atmosphere

In tetrahydrofuran; methanol; N,N-dimethyl-formamide;
DOI:10.1021/ja210861v

Reference yield:

: 846571-61-7
N-tosyl-2-[4-(ethylthio)-5-(2-cyanoethylthio)-(1,3)-dithiole-2-ylidene]-(1,3)-dithiolo[4,5-c]pyrrole

: 1357295-20-5
2-[4-(3,5-di-t-butylbenzylthio)-5-(ethylthio)-1,3-dithiole-2-ylidene]-5-{2-[2-(2-iodoethoxy)ethoxy]ethyl}-[1,3]dithiolo[4,5-c]pyrrole

Guidance literature:: Multi-step reaction with 3 steps

1.1: tetrahydrofuran / 0.5 h / Inert atmosphere

1.2: 24 h / 20 °C / Inert atmosphere

2.1: tetrahydrofuran; methanol / 0.33 h / Inert atmosphere

2.2: 0.5 h / 20 °C / Reflux; Inert atmosphere

3.1: N,N-dimethyl-formamide / 0.17 h / 20 °C / Inert atmosphere

3.2: 1 h / 20 °C / Inert atmosphere

In tetrahydrofuran; methanol; N,N-dimethyl-formamide;
DOI:10.1021/ja210861v