Technology Process of C73H130O16Si4
There total 9 articles about C73H130O16Si4 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
Multi-step reaction with 6 steps
1: K2CO3 / methanol
2: imidazoline; DMAP / CH2Cl2
3: 58 percent / OsO4; pyridine; H2S / diethyl ether / -78 - 20 °C
4: 70 percent / LAH / tetrahydrofuran / -78 °C
5: 80 percent / TMSOTf / CH2Cl2 / -20 °C
With
pyridine; 2-imidazoline; dmap; osmium(VIII) oxide; lithium aluminium tetrahydride; trimethylsilyl trifluoromethanesulfonate; hydrogen sulfide; potassium carbonate;
In
tetrahydrofuran; methanol; diethyl ether; dichloromethane;
4: Swern oxidation;
DOI:10.1016/j.tetlet.2007.03.001
- Guidance literature:
-
Multi-step reaction with 5 steps
1: imidazoline; DMAP / CH2Cl2
2: 58 percent / OsO4; pyridine; H2S / diethyl ether / -78 - 20 °C
3: 70 percent / LAH / tetrahydrofuran / -78 °C
4: 80 percent / TMSOTf / CH2Cl2 / -20 °C
With
pyridine; 2-imidazoline; dmap; osmium(VIII) oxide; lithium aluminium tetrahydride; trimethylsilyl trifluoromethanesulfonate; hydrogen sulfide;
In
tetrahydrofuran; diethyl ether; dichloromethane;
3: Swern oxidation;
DOI:10.1016/j.tetlet.2007.03.001
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 58 percent / OsO4; pyridine; H2S / diethyl ether / -78 - 20 °C
2: 70 percent / LAH / tetrahydrofuran / -78 °C
3: 80 percent / TMSOTf / CH2Cl2 / -20 °C
With
pyridine; osmium(VIII) oxide; lithium aluminium tetrahydride; trimethylsilyl trifluoromethanesulfonate; hydrogen sulfide;
In
tetrahydrofuran; diethyl ether; dichloromethane;
2: Swern oxidation;
DOI:10.1016/j.tetlet.2007.03.001