Benzyl-[1,7,7-trimethyl-bicyclo[2.2.1]hept-(2E)-ylidene]-amine

Base Information

• Chemical Name: Benzyl-[1,7,7-trimethyl-bicyclo[2.2.1]hept-(2E)-ylidene]-amine
• CAS No.: 145771-06-8
• Molecular Formula: C₁₇H₂₃N
• Molecular Weight: 241.376
• Mol file: 145771-06-8.mol

Synonyms:Benzyl-[1,7,7-trimethyl-bicyclo[2.2.1]hept-(2E)-ylidene]-amine

Chemical Property of Benzyl-[1,7,7-trimethyl-bicyclo[2.2.1]hept-(2E)-ylidene]-amine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Benzyl-[1,7,7-trimethyl-bicyclo[2.2.1]hept-(2E)-ylidene]-amine

There total 2 articles about Benzyl-[1,7,7-trimethyl-bicyclo[2.2.1]hept-(2E)-ylidene]-amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

(1R,4R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one (464-49-3,68546-28-1) + benzylamine (100-46-9) → N-(benzyl)-(D)-camphorimine (63765-03-7,145771-06-8)

Guidance literature:

With boron trifluoride diethyl etherate; In toluene; Heating;

Reference yield:

→ Benzyl-[1,7,7-trimethyl-bicyclo[2.2.1]hept-(2E)-ylidene]-amine (145771-06-8)

Guidance literature:

DOI:10.1055/s-1973-22251

Reference yield: 85.0%

Benzyl-[1,7,7-trimethyl-bicyclo[2.2.1]hept-(2E)-ylidene]-amine (145771-06-8) → N-Benzyl-1,7,7-trimethylbicyclo[2.2.1]heptan-2-amine

Guidance literature:

With zinc(II) tetrahydroborate; silica gel; In tetrahydrofuran; for 14h; Ambient temperature;

DOI:10.1021/jo961736a

upstream raw materials:

(1R,4R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one

benzylamine

Downstream raw materials:

Benzyl-((1S,2R)-1,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl)-amine

Benzyl-((1R,2S)-1,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl)-amine

2'-benzyl-1,7,7-trimethyl-spiro[bicyclo[2.2.1]heptane-2,3'-oxaziridine]

R,R,R-N-benzyl-camphorammonium tris(pentafluorophenyl)hydridoborate