1-Nitro-1-methyl-2-naphtylethene

Base Information

• Chemical Name: 1-Nitro-1-methyl-2-naphtylethene
• CAS No.: 59832-12-1
• Molecular Formula: C13H11NO2
• Molecular Weight: 213.2319
• NSC Number: 121155
• Mol file: 59832-12-1.mol

Synonyms:1-NITRO-1-METHYL-2-NAPHTYLETHENE;59832-12-1;37629-58-6;2-[(1E)-2-nitroprop-1-en-1-yl]naphthalene;(E)-2-(2-Nitroprop-1-en-1-yl)naphthalene;NSC121155;SCHEMBL8629342;MFCD03425382;NSC-121155;CS-0060737;EN300-21855629

Chemical Property of 1-Nitro-1-methyl-2-naphtylethene

Chemical Property:

• Vapor Pressure: 2.19E-05mmHg at 25°C
• Boiling Point: 371.6°Cat760mmHg
• Flash Point: 178.2°C
• PSA: 45.82000
• Density: 1.203g/cm³
• LogP: 4.00050
• XLogP3: 3.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 213.078978594
• Heavy Atom Count: 16
• Complexity: 293

Purity/Quality:

97% ^*data from raw suppliers

1-NITRO-1-METHYL-2-NAPHTHYLETHENE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC(=CC1=CC2=CC=CC=C2C=C1)[N+](=O)[O-]
• Isomeric SMILES: C/C(=C\C1=CC2=CC=CC=C2C=C1)/[N+](=O)[O-]

Technology Process of 1-Nitro-1-methyl-2-naphtylethene

There total 2 articles about 1-Nitro-1-methyl-2-naphtylethene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

Nitroethane (79-24-3) + β-naphthaldehyde (66-99-9) → 1-(β-naphthyl)-2-nitro-1-propene (59832-12-1)

Guidance literature:

With N-butylamine; In benzene; for 192h; Heating;

DOI:10.1021/jo00169a004

Reference yield:

→ 1-(β-naphthyl)-2-nitro-1-propene (59832-12-1)

Guidance literature:

Naphthalin-2-carbaldehyd, Nitroaethan in Eg., Ammoniumacetat, Erwaermen;

DOI:10.1139/v67-166

Reference yield: 67.0%

1-(β-naphthyl)-2-nitro-1-propene (59832-12-1) → (±)-1-(2-naphthyl)propan-2-amine (18085-03-5)

Guidance literature:

With lithium aluminium tetrahydride; In dichloromethane; at 80 ℃; for 48h;

DOI:10.1124/jpet.104.082503

upstream raw materials:

Nitroethane

β-naphthaldehyde

Downstream raw materials:

(±)-1-(2-naphthyl)propan-2-amine

1-methyl-2-(2-naphthyl)-ethylamine hydrochloride

4-methyl-5-(naphthalen-2-yl)-2-phenylthiazole