glutaric acid (4,5-dimethoxy-2-nitrobenzyl) ester (α,α-dideuterio-4-chloro-2-nitrobenzyl) ester

Base Information

Chemical Name:glutaric acid (4,5-dimethoxy-2-nitrobenzyl) ester (α,α-dideuterio-4-chloro-2-nitrobenzyl) ester
CAS No.:945920-71-8
Molecular Formula:C₂₁H₂₁ClN₂O₁₀
Molecular Weight:498.842
Hs Code.:

Synonyms:glutaric acid (4,5-dimethoxy-2-nitrobenzyl) ester (α,α-dideuterio-4-chloro-2-nitrobenzyl) ester

Suppliers and Price of glutaric acid (4,5-dimethoxy-2-nitrobenzyl) ester (α,α-dideuterio-4-chloro-2-nitrobenzyl) ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of glutaric acid (4,5-dimethoxy-2-nitrobenzyl) ester (α,α-dideuterio-4-chloro-2-nitrobenzyl) ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of glutaric acid (4,5-dimethoxy-2-nitrobenzyl) ester (α,α-dideuterio-4-chloro-2-nitrobenzyl) ester

There total 8 articles about glutaric acid (4,5-dimethoxy-2-nitrobenzyl) ester (α,α-dideuterio-4-chloro-2-nitrobenzyl) ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 457612-05-4
glutaric acid mono-(4,5-dimethoxy-2-nitrobenzyl) ester

: 945920-67-2
α,α-dideuterio-4-chloro-2-nitrobenzyl alcohol

: 945920-71-8
glutaric acid (4,5-dimethoxy-2-nitrobenzyl) ester (α,α-dideuterio-4-chloro-2-nitrobenzyl) ester

Guidance literature:: With dmap; dicyclohexyl-carbodiimide; In chloroform; at 60 ℃; for 24h;
DOI:10.1021/ja049686b

Reference yield:

: 1016-58-6
6-nitroveratryl alcohol

: 945920-71-8
glutaric acid (4,5-dimethoxy-2-nitrobenzyl) ester (α,α-dideuterio-4-chloro-2-nitrobenzyl) ester

Guidance literature:: Multi-step reaction with 2 steps

1: 56 percent / 4-dimethylaminopyridine; pyridine / 24 h / 50 °C

2: 87 percent / 4-dimethylaminopyridine; N,N'-dicyclohexylcarbodiimide / CHCl₃ / 24 h / 60 °C

With pyridine; dmap; dicyclohexyl-carbodiimide; In chloroform;
DOI:10.1021/ja049686b

Reference yield:

: 6280-88-2
4-chloro-2-nitro-benzoic acid

: 945920-71-8
glutaric acid (4,5-dimethoxy-2-nitrobenzyl) ester (α,α-dideuterio-4-chloro-2-nitrobenzyl) ester

Guidance literature:: Multi-step reaction with 3 steps

1: SOCl₂ / toluene / 3 h / Heating

2: 1.23 g / NaBD₄ / tetrahydrofuran; dimethylformamide / 24 h / 20 °C

3: 87 percent / 4-dimethylaminopyridine; N,N'-dicyclohexylcarbodiimide / CHCl₃ / 24 h / 60 °C

With dmap; thionyl chloride; sodium borodeuteride; dicyclohexyl-carbodiimide; In tetrahydrofuran; chloroform; N,N-dimethyl-formamide; toluene;
DOI:10.1021/ja049686b