1,6-anhydro-4-O-(4,6-O-benzylidene-β-D-glucopyranosyl)-2,3-O-(tetraisopropyldisiloxane-1,3-diyl)-β-D-glucopyranose

Base Information

Chemical Name:1,6-anhydro-4-O-(4,6-O-benzylidene-β-D-glucopyranosyl)-2,3-O-(tetraisopropyldisiloxane-1,3-diyl)-β-D-glucopyranose
CAS No.:97390-18-6
Molecular Formula:C₃₁H₅₀O₁₁Si₂
Molecular Weight:654.902
Hs Code.:

Synonyms:1,6-anhydro-4-O-(4,6-O-benzylidene-β-D-glucopyranosyl)-2,3-O-(tetraisopropyldisiloxane-1,3-diyl)-β-D-glucopyranose

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Chemical Property of 1,6-anhydro-4-O-(4,6-O-benzylidene-β-D-glucopyranosyl)-2,3-O-(tetraisopropyldisiloxane-1,3-diyl)-β-D-glucopyranose

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Technology Process of 1,6-anhydro-4-O-(4,6-O-benzylidene-β-D-glucopyranosyl)-2,3-O-(tetraisopropyldisiloxane-1,3-diyl)-β-D-glucopyranose

There total 7 articles about 1,6-anhydro-4-O-(4,6-O-benzylidene-β-D-glucopyranosyl)-2,3-O-(tetraisopropyldisiloxane-1,3-diyl)-β-D-glucopyranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 97390-16-4,99571-43-4
1,6-anhydro-2,3-O-(tetraisopropyldisiloxane-1,3-diyl)-4-O-(2,3-di-O-acetyl-4,6-O-benzylidene-β-D-glucopyranyl)-β-D-glucopyranose

: 97390-18-6
1,6-anhydro-4-O-(4,6-O-benzylidene-β-D-glucopyranosyl)-2,3-O-(tetraisopropyldisiloxane-1,3-diyl)-β-D-glucopyranose

Guidance literature:: With hydrazine hydrate; In methanol; for 10h; Ambient temperature;
DOI:10.1016/0008-6215(85)85222-8

Reference yield:

: 69304-37-6
1,3-Dichloro-1,1,3,3-tetraisopropyldisiloxane

: 97390-18-6
1,6-anhydro-4-O-(4,6-O-benzylidene-β-D-glucopyranosyl)-2,3-O-(tetraisopropyldisiloxane-1,3-diyl)-β-D-glucopyranose

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) pyridine; 2.) pyridine / 1.) r.t., 10 h; 2.) r.t., 6 h

2: 94 percent / hydrazine monohydrate / methanol; various solvent(s) / 10 h / Ambient temperature

With pyridine; hydrazine hydrate; In methanol;
DOI:10.1016/0008-6215(85)85222-8

Reference yield:

: 1125-88-8
benzaldehyde dimethyl acetal

: 97390-18-6
1,6-anhydro-4-O-(4,6-O-benzylidene-β-D-glucopyranosyl)-2,3-O-(tetraisopropyldisiloxane-1,3-diyl)-β-D-glucopyranose

Guidance literature:: Multi-step reaction with 3 steps

1: p-toluenesulfonic acid monohydrate / dimethylformamide / 1.5 h / 75 - 80 °C

2: 1.) pyridine; 2.) pyridine / 1.) r.t., 10 h; 2.) r.t., 6 h

3: 94 percent / hydrazine monohydrate / methanol; various solvent(s) / 10 h / Ambient temperature

With pyridine; toluene-4-sulfonic acid; hydrazine hydrate; In methanol; N,N-dimethyl-formamide;
DOI:10.1016/0008-6215(85)85222-8