1,3,4,5-tetra-O-benzyl-6-O-(2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl)-D-myo-inositol

Base Information

• Chemical Name: 1,3,4,5-tetra-O-benzyl-6-O-(2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl)-D-myo-inositol
• CAS No.: 297747-13-8
• Molecular Formula: C₆₈H₆₂O₁₅
• Molecular Weight: 1119.23

Synonyms:1,3,4,5-tetra-O-benzyl-6-O-(2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl)-D-myo-inositol

Chemical Property of 1,3,4,5-tetra-O-benzyl-6-O-(2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl)-D-myo-inositol

Chemical Property:

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Technology Process of 1,3,4,5-tetra-O-benzyl-6-O-(2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl)-D-myo-inositol

There total 1 articles about 1,3,4,5-tetra-O-benzyl-6-O-(2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl)-D-myo-inositol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

1,3,4,5-Tetra-O-benzyl-D-myo-inositol (261722-84-3) + (3aR,5R,6R,7S,7aR)-5-((benzoyloxy)methyl)-2-(pent-4-en-1-yloxy)-2-phenyltetrahydro-5H-[1,3]dioxolo[4,5-b]pyran-6,7-diyl dibenzoate (297747-11-6) → 1,3,4,5-tetra-O-benzyl-6-O-(2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl)-D-myo-inositol (297747-13-8)

Guidance literature:

With N-iodo-succinimide; 4 A molecular sieve; tert-butyldiphenylsilyl triflate; In dichloromethane; for 0.05h;

DOI:10.1071/CH01146

Reference yield: 82.0%

1,3,4,5-tetra-O-benzyl-6-O-(2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl)-D-myo-inositol (297747-13-8) → C70H64O16

Guidance literature:

With dmap; In pyridine; at 20 ℃;

DOI:10.1071/CH01146

Reference yield: 82.0%

acetic anhydride (108-24-7) + 1,3,4,5-tetra-O-benzyl-6-O-(2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl)-D-myo-inositol (297747-13-8) → C70H64O16

Guidance literature:

With pyridine; dmap; at 20 ℃; for 14h;

DOI:10.1021/ol0001214

upstream raw materials:

1,3,4,5-Tetra-O-benzyl-D-myo-inositol

(3aR,5R,6R,7S,7aR)-5-((benzoyloxy)methyl)-2-(pent-4-en-1-yloxy)-2-phenyltetrahydro-5H-[1,3]dioxolo[4,5-b]pyran-6,7-diyl dibenzoate

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