methyl (2R)-4,6-O-benzylidene-2-methyl-2-deoxy-α-D-threo-hex-3-ulopyranoside

Base Information

Chemical Name:methyl (2R)-4,6-O-benzylidene-2-methyl-2-deoxy-α-D-threo-hex-3-ulopyranoside
CAS No.:75837-51-3
Molecular Formula:C₁₅H₁₈O₅
Molecular Weight:278.305
Hs Code.:

Synonyms:methyl (2R)-4,6-O-benzylidene-2-methyl-2-deoxy-α-D-threo-hex-3-ulopyranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl (2R)-4,6-O-benzylidene-2-methyl-2-deoxy-α-D-threo-hex-3-ulopyranoside

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Technology Process of methyl (2R)-4,6-O-benzylidene-2-methyl-2-deoxy-α-D-threo-hex-3-ulopyranoside

There total 3 articles about methyl (2R)-4,6-O-benzylidene-2-methyl-2-deoxy-α-D-threo-hex-3-ulopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 75879-82-2
methyl 4,6-O-benzylidene-2-deoxy-2-C-methyl-α-D-idopyranoside

: 75837-51-3
methyl (2R)-4,6-O-benzylidene-2-methyl-2-deoxy-α-D-threo-hex-3-ulopyranoside

Guidance literature:: In acetic anhydride; dimethyl sulfoxide;
DOI:10.1039/c39800000721

Reference yield: 73.0%

: 19465-06-6,68907-47-1,75879-81-1,75879-82-2,75879-83-3,101978-79-4,130061-59-5
methyl 4,6-O-benzylidene-2-deoxy-2-C-methyl-α-D-altropyranoside

: 64526-80-3,64526-81-4,75837-51-3,109958-36-3,121467-58-1
methyl 4,6-O-benzylidene-2-deoxy-2-C-methyl-α-D-arabino-hexopyranosid-3-ulose

Guidance literature:: With Chloro-oxo-acetic acid; dimethyl sulfoxide; In dichloromethane; at -60 ℃; for 2h;

Reference yield:

: 2880-96-8,3150-15-0,3150-16-1,3257-59-8,14187-71-4,15384-57-3,19465-13-5,32976-15-1,52885-37-7,53270-02-3,53270-03-4,65391-11-9,65391-12-0,66537-92-6,67226-04-4,71184-14-0,86420-78-2,86420-79-3,91177-51-4,91177-52-5,117708-93-7,120408-72-2
methyl 2,3-anhydro-4,6-O-benzylidene-α-D-allopyranoside

: 64526-80-3,64526-81-4,75837-51-3,109958-36-3,121467-58-1
methyl 4,6-O-benzylidene-2-deoxy-2-C-methyl-α-D-arabino-hexopyranosid-3-ulose

Guidance literature:: Multi-step reaction with 2 steps

1: 56 percent / Cu(I)I / diethyl ether / 5 h / 0 °C

2: 73 percent / DMSO, oxalylchloride / CH₂Cl₂ / 2 h / -60 °C

With copper(l) iodide; Chloro-oxo-acetic acid; dimethyl sulfoxide; In diethyl ether; dichloromethane;