1-(2,5-anhydro-1-deoxy-6-sulfo-D-glucitolyl)-4-(4-N,N-dimethylaminophenyl)-[1,2,3]-triazole

Base Information

Chemical Name:1-(2,5-anhydro-1-deoxy-6-sulfo-D-glucitolyl)-4-(4-N,N-dimethylaminophenyl)-[1,2,3]-triazole
CAS No.:1309856-24-3
Molecular Formula:C₁₆H₂₂N₄O₇S
Molecular Weight:414.439
Hs Code.:

Synonyms:1-(2,5-anhydro-1-deoxy-6-sulfo-D-glucitolyl)-4-(4-N,N-dimethylaminophenyl)-[1,2,3]-triazole

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Chemical Property of 1-(2,5-anhydro-1-deoxy-6-sulfo-D-glucitolyl)-4-(4-N,N-dimethylaminophenyl)-[1,2,3]-triazole

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Technology Process of 1-(2,5-anhydro-1-deoxy-6-sulfo-D-glucitolyl)-4-(4-N,N-dimethylaminophenyl)-[1,2,3]-triazole

There total 8 articles about 1-(2,5-anhydro-1-deoxy-6-sulfo-D-glucitolyl)-4-(4-N,N-dimethylaminophenyl)-[1,2,3]-triazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 33.0%

: 1309856-11-8
1-(2,5-anhydro-1-deoxy-D-glucitolyl)-4-(4-N,N-dimethylaminophenyl)-[1,2,3]-triazole

: 1309856-24-3
1-(2,5-anhydro-1-deoxy-6-sulfo-D-glucitolyl)-4-(4-N,N-dimethylaminophenyl)-[1,2,3]-triazole

Guidance literature:: With sulfur trioxide pyridine complex; In pyridine; at 0 - 4 ℃; for 16h;
DOI:10.1016/j.tetlet.2011.03.090

Reference yield:

: 1309924-07-9
3,4,6-tri-O-acetyl-2,5-anhydro-1-azido-1-deoxy-D-glucitol

: 1309856-24-3
1-(2,5-anhydro-1-deoxy-6-sulfo-D-glucitolyl)-4-(4-N,N-dimethylaminophenyl)-[1,2,3]-triazole

Guidance literature:: Multi-step reaction with 3 steps

1: sodium 2-(1,2-dihydroxyethyl)-4-hydroxy-5-oxo-2,5-dihydro-furan-3-olate; copper(II) sulphate hydrate / water; isopropyl alcohol / 2 h / 40 - 50 °C

2: sodium methylate / methanol / 0.25 h / 20 °C / Inert atmosphere

3: sulfur trioxide pyridine complex / pyridine / 16 h / 0 - 4 °C

With sodium 2-(1,2-dihydroxyethyl)-4-hydroxy-5-oxo-2,5-dihydro-furan-3-olate; copper(II) sulphate hydrate; sodium methylate; sulfur trioxide pyridine complex; In pyridine; methanol; water; isopropyl alcohol;
DOI:10.1016/j.tetlet.2011.03.090

Reference yield:

: 1309924-06-8
2,5-anhydro-1-bromo-1-deoxy-D-glucitol

: 1309856-24-3
1-(2,5-anhydro-1-deoxy-6-sulfo-D-glucitolyl)-4-(4-N,N-dimethylaminophenyl)-[1,2,3]-triazole

Guidance literature:: Multi-step reaction with 5 steps

1: sodium azide / water; N,N-dimethyl-formamide / 12 h / 90 - 100 °C

2: pyridine / 3 h / 20 °C / Inert atmosphere

3: sodium 2-(1,2-dihydroxyethyl)-4-hydroxy-5-oxo-2,5-dihydro-furan-3-olate; copper(II) sulphate hydrate / water; isopropyl alcohol / 2 h / 40 - 50 °C

4: sodium methylate / methanol / 0.25 h / 20 °C / Inert atmosphere

5: sulfur trioxide pyridine complex / pyridine / 16 h / 0 - 4 °C

With pyridine; sodium azide; sodium 2-(1,2-dihydroxyethyl)-4-hydroxy-5-oxo-2,5-dihydro-furan-3-olate; copper(II) sulphate hydrate; sodium methylate; sulfur trioxide pyridine complex; In pyridine; methanol; water; N,N-dimethyl-formamide; isopropyl alcohol;
DOI:10.1016/j.tetlet.2011.03.090