1,1,1-tris(phenylthio)-2-<(methoxycarbonyl)oxy>-3-<(trimethylsilyl)methyl>-3-butene

Base Information

• Chemical Name: 1,1,1-tris(phenylthio)-2-<(methoxycarbonyl)oxy>-3-<(trimethylsilyl)methyl>-3-butene
• CAS No.: 135619-37-3
• Molecular Formula: C₂₈H₃₂O₃S₃Si
• Molecular Weight: 540.844

Synonyms:1,1,1-tris(phenylthio)-2-<(methoxycarbonyl)oxy>-3-<(trimethylsilyl)methyl>-3-butene

Chemical Property of 1,1,1-tris(phenylthio)-2-<(methoxycarbonyl)oxy>-3-<(trimethylsilyl)methyl>-3-butene

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of 1,1,1-tris(phenylthio)-2-<(methoxycarbonyl)oxy>-3-<(trimethylsilyl)methyl>-3-butene

There total 3 articles about 1,1,1-tris(phenylthio)-2-<(methoxycarbonyl)oxy>-3-<(trimethylsilyl)methyl>-3-butene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tris(phenylthio)methane (4832-52-4) → 1,1,1-tris(phenylthio)-2-<(methoxycarbonyl)oxy>-3-<(trimethylsilyl)methyl>-3-butene (135619-37-3)

Guidance literature:

Multi-step reaction with 3 steps

1: 1.) n-BuLi / 1.) THF, hexane, -78 deg C, 2.) THF, hexane, -78 deg C to RT

2: 1.) (COCl)2, DMSO, 2.) Et₃N / 1.) CH₂Cl₂, -78 deg C, 30 min, 2.) CH₂Cl₂, -78 deg C to RT

With n-butyllithium; oxalyl dichloride; dimethyl sulfoxide; triethylamine;

DOI:10.1021/ja00019a037

Reference yield:

2,2,2-tris(phenylthio)ethanol (135619-35-1) → 1,1,1-tris(phenylthio)-2-<(methoxycarbonyl)oxy>-3-<(trimethylsilyl)methyl>-3-butene (135619-37-3)

Guidance literature:

Multi-step reaction with 2 steps

1: 1.) (COCl)2, DMSO, 2.) Et₃N / 1.) CH₂Cl₂, -78 deg C, 30 min, 2.) CH₂Cl₂, -78 deg C to RT

With oxalyl dichloride; dimethyl sulfoxide; triethylamine;

DOI:10.1021/ja00019a037

Reference yield:

(2-bromoallyl)trimethylsilane (81790-10-5) + 2,2,2-tris(phenylthio)acetaldehyde (96014-41-4) + methyl chloroformate (79-22-1) → 1,1,1-tris(phenylthio)-2-<(methoxycarbonyl)oxy>-3-<(trimethylsilyl)methyl>-3-butene (135619-37-3)

Guidance literature:

Yield given. Multistep reaction;

DOI:10.1021/ja00019a037

upstream raw materials:

(2-bromoallyl)trimethylsilane

2,2,2-tris(phenylthio)acetaldehyde

methyl chloroformate

tris(phenylthio)methane

Downstream raw materials:

(1R^*,4R^*,10R^*,13R^*)-12-methylene-10-(phenylsulfonyl)-2-oxo-3-oxatricyclo<8.2.1.0^4,13>tridecane

(1S^*,4S^*,10R^*,13S^*)-12-methylene-10-(phenylsulfonyl)-2-oxo-3-oxatricyclo<8.2.1.0^4,13>tridecane

(1R^*,4R^*,9R^*,12R^*)-11-methylene-9-(phenylsulfonyl)-2-oxo-3-oxatricyclo<7.2.1.0^4,12>dodecane

(1S^*,4S^*,9R^*,12S^*)-11-methylene-9-(phenylsulfonyl)-2-oxo-3-oxatricyclo<7.2.1.0^4,12>dodecane

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