C₆₀H₄₀N₂SSi

Base Information

• Chemical Name: C₆₀H₄₀N₂SSi
• CAS No.: 1414941-62-0
• Molecular Formula: C₆₀H₄₀N₂SSi
• Molecular Weight: 849.143
• Mol file: 1414941-62-0.mol

Synonyms:C₆₀H₄₀N₂SSi

Chemical Property of C₆₀H₄₀N₂SSi

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₆₀H₄₀N₂SSi

There total 4 articles about C₆₀H₄₀N₂SSi which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

(4-bromophenyl)(4-(dibenzo[b,d]thiophen-4-yl)phenyl)diphenylsilane (1414941-68-6) + 9-(9H-carbazol-3-yl)-9H-carbazole (18628-07-4) → C60H40N2SSi (1414941-62-0)

Guidance literature:

With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; sodium t-butanolate; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; In xylene; at 140 ℃; Reflux;

Reference yield:

bis(4-bromophenyl)(diphenyl)silane (18733-91-0) → C60H40N2SSi (1414941-62-0)

Guidance literature:

Multi-step reaction with 2 steps

1: potassium carbonate / tetrakis(triphenylphosphine) palladium⁽⁰⁾ / toluene; water / 90 °C / Inert atmosphere

2: sodium t-butanolate; dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane / tris-(dibenzylideneacetone)dipalladium⁽⁰⁾ / xylene / 140 °C / Reflux

With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium carbonate; sodium t-butanolate; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In water; toluene; xylene;

Reference yield:

1.4-dibromobenzene (106-37-6) → C60H40N2SSi (1414941-62-0)

Guidance literature:

Multi-step reaction with 3 steps

1: n-butyllithium / hexane; diethyl ether / 3.5 h / -78 °C

2: potassium carbonate / tetrakis(triphenylphosphine) palladium⁽⁰⁾ / toluene; water / 90 °C / Inert atmosphere

3: sodium t-butanolate; dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane / tris-(dibenzylideneacetone)dipalladium⁽⁰⁾ / xylene / 140 °C / Reflux

With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; n-butyllithium; potassium carbonate; sodium t-butanolate; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In diethyl ether; hexane; water; toluene; xylene;

upstream raw materials:

1.4-dibromobenzene

diphenylsilyl dichloride

(4-bromophenyl)(4-(dibenzo[b,d]thiophen-4-yl)phenyl)diphenylsilane

9-(9H-carbazol-3-yl)-9H-carbazole