C₅₉H₉₀O₉Si₂

Base Information

Chemical Name:C₅₉H₉₀O₉Si₂
CAS No.:1373634-33-3
Molecular Formula:C₅₉H₉₀O₉Si₂
Molecular Weight:999.529
Hs Code.:

C<sub>59</sub>H<sub>90</sub>O<sub>9</sub>Si<sub>2</sub>

Synonyms:C₅₉H₉₀O₉Si₂

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Chemical Property of C₅₉H₉₀O₉Si₂

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Technology Process of C₅₉H₉₀O₉Si₂

There total 16 articles about C₅₉H₉₀O₉Si₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₆₉H₁₁₁BO₈Si₂

: 1373634-33-3
C₅₉H₉₀O₉Si₂

Guidance literature:: With water; dihydrogen peroxide; sodium hydroxide; In tetrahydrofuran; hexane; at 20 ℃; for 0.5h; Inert atmosphere;
DOI:10.1021/ol300672q

Reference yield:

: 1191256-12-8
C₂₅H₂₆O₇

: 1373634-33-3
C₅₉H₉₀O₉Si₂

Guidance literature:: Multi-step reaction with 15 steps

1.1: lithium hexamethyldisilazane / tetrahydrofuran; toluene / 0.17 h / 0 - 20 °C / Inert atmosphere

1.2: 0.67 h / 20 °C / Inert atmosphere

2.1: osmium(VIII) oxide; water; 4-methylmorpholine N-oxide / dichloromethane / 1.5 h / 20 °C / Inert atmosphere

3.1: sodium periodate; sodium hydrogencarbonate / dichloromethane; water / 20 °C / Inert atmosphere

4.1: sodium tetrahydroborate / methanol / 0.17 h / 0 °C / Inert atmosphere

5.1: Crabtree's catalyst; hydrogen / dichloromethane / 0 °C / Inert atmosphere

6.1: sodium hydrogencarbonate; Dess-Martin periodane / dichloromethane / 1 h / 20 °C / Inert atmosphere

7.1: chromium dichloride; manganese; zirconocene dichloride; N-(2-((S)-4-isopropyl-4,5-dihydrooxazol-2-yl)-6-(((1S,2R,5S)-2-isopropyl-5-methylcyclohexyl)oxy)phenyl)benzenesulfonamide; N,N,N',N'-tetramethyl-1,8-diaminonaphthalene; lithium chloride / acetonitrile / 4 h / 20 °C / Inert atmosphere

8.1: triethylsilane; triethylsilyl trifluoromethyl sulfonate / acetonitrile / 0.33 h / -40 °C / Inert atmosphere

9.1: sodium hydrogencarbonate; Dess-Martin periodane / dichloromethane / 1 h / 20 °C / Inert atmosphere

10.1: chromium dichloride; manganese; zirconocene dichloride; C₂₆H₃₂Cl₂N₂O₄S; N,N,N',N'-tetramethyl-1,8-diaminonaphthalene; lithium chloride / acetonitrile / 3 h / 20 °C / Inert atmosphere

11.1: 18-crown-6 ether; potassium hydride / toluene / 24 h / 0 - 20 °C / Inert atmosphere

12.1: diisobutylaluminium hydride / toluene / 3 h / -78 °C / Inert atmosphere

13.1: pyridine; silver nitrate / N,N-dimethyl-formamide / 2 h / 20 °C / Inert atmosphere

14.1: n-butyllithium / tetrahydrofuran; hexane / 0.25 h / -78 - 0 °C / Inert atmosphere

14.2: 0 - 20 °C / Inert atmosphere

15.1: water; dihydrogen peroxide; sodium hydroxide / tetrahydrofuran; hexane / 0.5 h / 20 °C / Inert atmosphere

With pyridine; chromium dichloride; triethylsilane; manganese; sodium tetrahydroborate; sodium periodate; osmium(VIII) oxide; n-butyllithium; zirconocene dichloride; Crabtree's catalyst; 18-crown-6 ether; N-(2-((S)-4-isopropyl-4,5-dihydrooxazol-2-yl)-6-(((1S,2R,5S)-2-isopropyl-5-methylcyclohexyl)oxy)phenyl)benzenesulfonamide; C₂₆H₃₂Cl₂N₂O₄S; water; hydrogen; dihydrogen peroxide; triethylsilyl trifluoromethyl sulfonate; potassium hydride; N,N,N',N'-tetramethyl-1,8-diaminonaphthalene; diisobutylaluminium hydride; sodium hydrogencarbonate; Dess-Martin periodane; silver nitrate; 4-methylmorpholine N-oxide; lithium chloride; sodium hydroxide; lithium hexamethyldisilazane; In tetrahydrofuran; methanol; hexane; dichloromethane; water; N,N-dimethyl-formamide; toluene; acetonitrile;
DOI:10.1021/ol300672q

Reference yield:

: 1373634-51-5
C₃₂H₃₁FO₈S

: 1373634-33-3
C₅₉H₉₀O₉Si₂

Guidance literature:: Multi-step reaction with 14 steps

1.1: osmium(VIII) oxide; water; 4-methylmorpholine N-oxide / dichloromethane / 1.5 h / 20 °C / Inert atmosphere

2.1: sodium periodate; sodium hydrogencarbonate / dichloromethane; water / 20 °C / Inert atmosphere

3.1: sodium tetrahydroborate / methanol / 0.17 h / 0 °C / Inert atmosphere

4.1: Crabtree's catalyst; hydrogen / dichloromethane / 0 °C / Inert atmosphere

5.1: sodium hydrogencarbonate; Dess-Martin periodane / dichloromethane / 1 h / 20 °C / Inert atmosphere

6.1: chromium dichloride; manganese; zirconocene dichloride; N-(2-((S)-4-isopropyl-4,5-dihydrooxazol-2-yl)-6-(((1S,2R,5S)-2-isopropyl-5-methylcyclohexyl)oxy)phenyl)benzenesulfonamide; N,N,N',N'-tetramethyl-1,8-diaminonaphthalene; lithium chloride / acetonitrile / 4 h / 20 °C / Inert atmosphere

7.1: triethylsilane; triethylsilyl trifluoromethyl sulfonate / acetonitrile / 0.33 h / -40 °C / Inert atmosphere

8.1: sodium hydrogencarbonate; Dess-Martin periodane / dichloromethane / 1 h / 20 °C / Inert atmosphere

9.1: chromium dichloride; manganese; zirconocene dichloride; C₂₆H₃₂Cl₂N₂O₄S; N,N,N',N'-tetramethyl-1,8-diaminonaphthalene; lithium chloride / acetonitrile / 3 h / 20 °C / Inert atmosphere

10.1: 18-crown-6 ether; potassium hydride / toluene / 24 h / 0 - 20 °C / Inert atmosphere

11.1: diisobutylaluminium hydride / toluene / 3 h / -78 °C / Inert atmosphere

12.1: pyridine; silver nitrate / N,N-dimethyl-formamide / 2 h / 20 °C / Inert atmosphere

13.1: n-butyllithium / tetrahydrofuran; hexane / 0.25 h / -78 - 0 °C / Inert atmosphere

13.2: 0 - 20 °C / Inert atmosphere

14.1: water; dihydrogen peroxide; sodium hydroxide / tetrahydrofuran; hexane / 0.5 h / 20 °C / Inert atmosphere

With pyridine; chromium dichloride; triethylsilane; manganese; sodium tetrahydroborate; sodium periodate; osmium(VIII) oxide; n-butyllithium; zirconocene dichloride; Crabtree's catalyst; 18-crown-6 ether; N-(2-((S)-4-isopropyl-4,5-dihydrooxazol-2-yl)-6-(((1S,2R,5S)-2-isopropyl-5-methylcyclohexyl)oxy)phenyl)benzenesulfonamide; C₂₆H₃₂Cl₂N₂O₄S; water; hydrogen; dihydrogen peroxide; triethylsilyl trifluoromethyl sulfonate; potassium hydride; N,N,N',N'-tetramethyl-1,8-diaminonaphthalene; diisobutylaluminium hydride; sodium hydrogencarbonate; Dess-Martin periodane; silver nitrate; 4-methylmorpholine N-oxide; lithium chloride; sodium hydroxide; In tetrahydrofuran; methanol; hexane; dichloromethane; water; N,N-dimethyl-formamide; toluene; acetonitrile;
DOI:10.1021/ol300672q