Benzene-1,2-disulfonyl diazide

Base Information

• Chemical Name: Benzene-1,2-disulfonyl diazide
• CAS No.: 21691-17-8
• Molecular Formula: C6H6N6O4S2+2
• Molecular Weight: 290.2785
• NSC Number: 122232
• DSSTox Substance ID: DTXSID20393603
• Mol file: 21691-17-8.mol

Synonyms:benzene-1,2-disulfonyl diazide;21691-17-8;1-N,2-N-didiazobenzene-1,2-disulfonamide;Benzenedisulfonyl diazide;o-Benzenedisulfonyl azide;1,2-benzenedisulfonylazide;benzene-1,2-disulfonyl azide;SCHEMBL10616438;DTXSID20393603;YUDYNAYYRODHGK-UHFFFAOYSA-N;MFCD13181904;NSC122232;AKOS015955197;NSC-122232

Chemical Property of Benzene-1,2-disulfonyl diazide

Chemical Property:

• XLogP3: 2.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 8
• Rotatable Bond Count: 4
• Exact Mass: 287.97354498
• Heavy Atom Count: 18
• Complexity: 545

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C(=C1)S(=O)(=O)N=[N+]=[N-])S(=O)(=O)N=[N+]=[N-]

Technology Process of Benzene-1,2-disulfonyl diazide

There total 3 articles about Benzene-1,2-disulfonyl diazide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,2-benzenedisulfonyl dichloride (6461-76-3) → benzene-1,2-disulfonyl diazide (21691-17-8)

Guidance literature:

With sodium azide;

DOI:10.1021/jo00895a015

Reference yield:

C6H10N4O4S2 (21691-16-7) → benzene-1,2-disulfonyl diazide (21691-17-8)

Guidance literature:

With sulfuric acid; sodium nitrite;

DOI:10.1021/jo01263a048

Reference yield:

2-amino-1-benzenesulfonic acid (88-21-1) → benzene-1,2-disulfonyl diazide (21691-17-8)

Guidance literature:

Multi-step reaction with 2 steps

1: (i) aq. HCl, NaNO₂, (ii) CuCl₂, SO₂, (iii) SOCl₂

2: NaN₃

With sodium azide;

DOI:10.1021/jo00895a015

upstream raw materials:

C₆H₁₀N₄O₄S₂

1,2-benzenedisulfonyl dichloride

2-amino-1-benzenesulfonic acid

Downstream raw materials:

1,2-bis(phenylsulphonyl)benzene

benzene-1,2-disulfonamide

Benzolsulfonylanilid-o-sulfonamid

benzene-1,2-disulfonic acid bis-cyclohex-1-enylamide