(η5-1,2,3,4,5-pentakis(carbomethoxy)cyclopentadienyl)tricarbonylmanganese(I)

Base Information

• Chemical Name: (η5-1,2,3,4,5-pentakis(carbomethoxy)cyclopentadienyl)tricarbonylmanganese(I)
• CAS No.: 91043-17-3
• Molecular Formula: C₁₈H₁₅MnO₁₃
• Molecular Weight: 494.247
• Mol file: 91043-17-3.mol

Synonyms:(η5-1,2,3,4,5-pentakis(carbomethoxy)cyclopentadienyl)tricarbonylmanganese(I)

Chemical Property of (η5-1,2,3,4,5-pentakis(carbomethoxy)cyclopentadienyl)tricarbonylmanganese(I)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (η5-1,2,3,4,5-pentakis(carbomethoxy)cyclopentadienyl)tricarbonylmanganese(I)

There total 1 articles about (η5-1,2,3,4,5-pentakis(carbomethoxy)cyclopentadienyl)tricarbonylmanganese(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

bromopentacarbonylmanganese(I) (14516-54-2) + potassium 1,2,3,4,5-pentakis(methoxycarbonyl)cyclopentadienide (16691-64-8) → dimanganese decacarbonyl (10170-69-1) + (η5-1,2,3,4,5-pentakis(carbomethoxy)cyclopentadienyl)tricarbonylmanganese(I) (91043-17-3)

Guidance literature:

In methanol; heated under N2 at 40-50°C for 24 h; evapn. under reduced pressure, extrn. (methylene chloride), evapn.,chromy. (silica gel column, CH2C2/CH3OH 9/1);

DOI:10.1016/0022-328X(84)80092-3

Reference yield:

(η5-1,2,3,4,5-pentakis(carbomethoxy)cyclopentadienyl)tricarbonylmanganese(I) (91043-17-3) → Mn(CO)2(C5(CO2CH3)5)(P(C6H5)3) (91043-19-5)

Guidance literature:

With triphenylphosphine; In acetone; Irradiation (UV/VIS); under N2 for 1 h at 25°C; evapn. under reduced pressure;

DOI:10.1016/0022-328X(84)80092-3

upstream raw materials:

bromopentacarbonylmanganese(I)

potassium 1,2,3,4,5-pentakis(methoxycarbonyl)cyclopentadienide

Downstream raw materials:

Mn(CO)2(C₅(CO₂CH₃)5)(P(C₆H₅)3)