p-methylphenyl 5-O-(2,3,5-tri-O-benzoyl-α-D-arabinofuranosyl)-2,3-di-O-benzoyl-1-thio-α-D-arabinofuranoside

Base Information

Chemical Name:p-methylphenyl 5-O-(2,3,5-tri-O-benzoyl-α-D-arabinofuranosyl)-2,3-di-O-benzoyl-1-thio-α-D-arabinofuranoside
CAS No.:1207338-49-5
Molecular Formula:C₅₂H₄₄O₁₃S
Molecular Weight:908.98
Hs Code.:

Synonyms:p-methylphenyl 5-O-(2,3,5-tri-O-benzoyl-α-D-arabinofuranosyl)-2,3-di-O-benzoyl-1-thio-α-D-arabinofuranoside

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Chemical Property of p-methylphenyl 5-O-(2,3,5-tri-O-benzoyl-α-D-arabinofuranosyl)-2,3-di-O-benzoyl-1-thio-α-D-arabinofuranoside

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Technology Process of p-methylphenyl 5-O-(2,3,5-tri-O-benzoyl-α-D-arabinofuranosyl)-2,3-di-O-benzoyl-1-thio-α-D-arabinofuranoside

There total 4 articles about p-methylphenyl 5-O-(2,3,5-tri-O-benzoyl-α-D-arabinofuranosyl)-2,3-di-O-benzoyl-1-thio-α-D-arabinofuranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 1207338-48-4
2,3,5-tri-O-benzoyl-D-arabinofuranosyl trichloroacetimidate

: 685111-68-6
p-toluyl 2,3-di-O-benzoyl-1-thio-α-D-arabinofuranoside

: 1207338-49-5
p-methylphenyl 5-O-(2,3,5-tri-O-benzoyl-α-D-arabinofuranosyl)-2,3-di-O-benzoyl-1-thio-α-D-arabinofuranoside

Guidance literature:: With trimethylsilyl trifluoromethanesulfonate; In dichloromethane; at -20 - 0 ℃; chemoselective reaction; Molecular sieve; Inert atmosphere;
DOI:10.1016/j.tet.2009.11.038

Reference yield:

: p-tolyl-5-O-acetyl-1-thio-α-D-arabinofuranoside

: 1207338-49-5
p-methylphenyl 5-O-(2,3,5-tri-O-benzoyl-α-D-arabinofuranosyl)-2,3-di-O-benzoyl-1-thio-α-D-arabinofuranoside

Guidance literature:: Multi-step reaction with 3 steps

1: pyridine / dichloromethane / 12 h / 0 °C

2: acetyl chloride / methanol; dichloromethane / 4 h / 20 °C

3: boron trifluoride diethyl etherate / dichloromethane / 0.5 h / 20 °C / Molecular sieve; Inert atmosphere

With pyridine; boron trifluoride diethyl etherate; acetyl chloride; In methanol; dichloromethane;
DOI:10.1093/glycob/cwr068

Reference yield:

: C₂₈H₂₆O₇S

: 1207338-49-5
p-methylphenyl 5-O-(2,3,5-tri-O-benzoyl-α-D-arabinofuranosyl)-2,3-di-O-benzoyl-1-thio-α-D-arabinofuranoside

Guidance literature:: Multi-step reaction with 2 steps

1: acetyl chloride / methanol; dichloromethane / 4 h / 20 °C

2: boron trifluoride diethyl etherate / dichloromethane / 0.5 h / 20 °C / Molecular sieve; Inert atmosphere

With boron trifluoride diethyl etherate; acetyl chloride; In methanol; dichloromethane;
DOI:10.1093/glycob/cwr068