Dimethyl-carbamic acid (3S,4S,4aS,6R,7S,8S,8aS,9aS,10R,10aS)-3,4,10-tris-benzyloxy-8-chloro-6-(3,4-dimethoxy-benzyloxy)-3-methyl-decahydro-1,5,9-trioxa-anthracen-7-yl ester

Base Information

Chemical Name:Dimethyl-carbamic acid (3S,4S,4aS,6R,7S,8S,8aS,9aS,10R,10aS)-3,4,10-tris-benzyloxy-8-chloro-6-(3,4-dimethoxy-benzyloxy)-3-methyl-decahydro-1,5,9-trioxa-anthracen-7-yl ester
CAS No.:110115-21-4
Molecular Formula:C₄₅H₅₂ClNO₁₁
Molecular Weight:818.361
Hs Code.:

Dimethyl-carbamic acid (3S,4S,4aS,6R,7S,8S,8aS,9aS,10R,10aS)-3,4,10-tris-benzyloxy-8-chloro-6-(3,4-dimethoxy-benzyloxy)-3-methyl-decahydro-1,5,9-trioxa-anthracen-7-yl ester

Synonyms:Dimethyl-carbamic acid (3S,4S,4aS,6R,7S,8S,8aS,9aS,10R,10aS)-3,4,10-tris-benzyloxy-8-chloro-6-(3,4-dimethoxy-benzyloxy)-3-methyl-decahydro-1,5,9-trioxa-anthracen-7-yl ester

Suppliers and Price of Dimethyl-carbamic acid (3S,4S,4aS,6R,7S,8S,8aS,9aS,10R,10aS)-3,4,10-tris-benzyloxy-8-chloro-6-(3,4-dimethoxy-benzyloxy)-3-methyl-decahydro-1,5,9-trioxa-anthracen-7-yl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Dimethyl-carbamic acid (3S,4S,4aS,6R,7S,8S,8aS,9aS,10R,10aS)-3,4,10-tris-benzyloxy-8-chloro-6-(3,4-dimethoxy-benzyloxy)-3-methyl-decahydro-1,5,9-trioxa-anthracen-7-yl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Dimethyl-carbamic acid (3S,4S,4aS,6R,7S,8S,8aS,9aS,10R,10aS)-3,4,10-tris-benzyloxy-8-chloro-6-(3,4-dimethoxy-benzyloxy)-3-methyl-decahydro-1,5,9-trioxa-anthracen-7-yl ester

There total 8 articles about Dimethyl-carbamic acid (3S,4S,4aS,6R,7S,8S,8aS,9aS,10R,10aS)-3,4,10-tris-benzyloxy-8-chloro-6-(3,4-dimethoxy-benzyloxy)-3-methyl-decahydro-1,5,9-trioxa-anthracen-7-yl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 33842-02-3,529510-96-1
dichloromethylenedimethyliminium chloride

: 110115-20-3
(3S,4S,4aS,6R,7R,8S,8aR,9aS,10R,10aS)-3,4,10-Tris-benzyloxy-6-(3,4-dimethoxy-benzyloxy)-3-methyl-decahydro-1,5,9-trioxa-anthracene-7,8-diol

: 110115-21-4
Dimethyl-carbamic acid (3S,4S,4aS,6R,7S,8S,8aS,9aS,10R,10aS)-3,4,10-tris-benzyloxy-8-chloro-6-(3,4-dimethoxy-benzyloxy)-3-methyl-decahydro-1,5,9-trioxa-anthracen-7-yl ester

Guidance literature:: With triethylamine; In 1,2-dichloro-ethane; for 1h; Heating;
DOI:10.1021/jo00229a014

Reference yield:

: 110046-71-4
3-O-benzyl-2-deoxy-2-C-(L-threo-1',2'-dibenzyloxy-2'-methylpropane-1',3'-diyl)-α-D-glucopyranoside

: 110115-21-4
Dimethyl-carbamic acid (3S,4S,4aS,6R,7S,8S,8aS,9aS,10R,10aS)-3,4,10-tris-benzyloxy-8-chloro-6-(3,4-dimethoxy-benzyloxy)-3-methyl-decahydro-1,5,9-trioxa-anthracen-7-yl ester

Guidance literature:: Multi-step reaction with 8 steps

1: triethylamine, 4-(dimethylamino)pyridine / CH₂Cl₂ / 16 h / Ambient temperature

2: pyridinium p-toluenesulfonate / CH₂Cl₂

3: tetra-n-butylammonium fluoride / tetrahydrofuran / 3 h / Ambient temperature

4: 75 percent / pyridinium chlorochromate / benzene / Heating

5: tetrahydrofuran / 0.5 h / Ambient temperature

6: 59 percent / pyridinium p-toluenesulfonate / benzene / 24 h / Heating

7: 62 percent / N-methylmorpholine N-oxide, osmium tetraoxide / 2-methyl-propan-2-ol; acetone; H₂O / 48 h / Ambient temperature

8: 89 percent / triethylamine / 1,2-dichloro-ethane / 1 h / Heating

With dmap; osmium(VIII) oxide; tetrabutyl ammonium fluoride; pyridinium p-toluenesulfonate; 4-methylmorpholine N-oxide; triethylamine; pyridinium chlorochromate; In tetrahydrofuran; dichloromethane; water; 1,2-dichloro-ethane; acetone; tert-butyl alcohol; benzene;
DOI:10.1021/jo00229a014

Reference yield:

: (2S,3S,4R,4aS,5S,6S,8aS)-4,5,6-Tris-benzyloxy-3-(2-ethoxy-ethoxy)-6-methyl-hexahydro-pyrano[2,3-b]pyran-2-carbaldehyde

: 110115-21-4
Dimethyl-carbamic acid (3S,4S,4aS,6R,7S,8S,8aS,9aS,10R,10aS)-3,4,10-tris-benzyloxy-8-chloro-6-(3,4-dimethoxy-benzyloxy)-3-methyl-decahydro-1,5,9-trioxa-anthracen-7-yl ester

Guidance literature:: Multi-step reaction with 4 steps

1: tetrahydrofuran / 0.5 h / Ambient temperature

2: 59 percent / pyridinium p-toluenesulfonate / benzene / 24 h / Heating

3: 62 percent / N-methylmorpholine N-oxide, osmium tetraoxide / 2-methyl-propan-2-ol; acetone; H₂O / 48 h / Ambient temperature

4: 89 percent / triethylamine / 1,2-dichloro-ethane / 1 h / Heating

With osmium(VIII) oxide; pyridinium p-toluenesulfonate; 4-methylmorpholine N-oxide; triethylamine; In tetrahydrofuran; water; 1,2-dichloro-ethane; acetone; tert-butyl alcohol; benzene;
DOI:10.1021/jo00229a014