(R)-Marmin

Base Information

Chemical Name:(R)-Marmin
CAS No.:5980-09-6
Molecular Formula:C₁₉H₂₄O₅
Molecular Weight:332.397
Hs Code.:
NSC Number:126257
Nikkaji Number:J103.666A
Metabolomics Workbench ID:44561
Mol file:5980-09-6.mol

Synonyms:(R)-Marmin;5980-09-6;7-[(E)-6,7-dihydroxy-3,7-dimethyloct-2-enoxy]chromen-2-one;7-[(6,7-Dihydroxy-3,7-dimethyl-2-octen-1-yl)oxy]coumarin;NSC126257;CHEBI:172558;AKOS032948851;NSC-126257;Coumarin 7-[(6,7-dimethyl-2-octenyl)oxy];Coumarin,7-dihydroxy-3,7-dimethyl-2-octenyl)oxy]-;7-{[(2E)-6,7-dihydroxy-3,7-dimethyloct-2-en-1-yl]oxy}-2H-chromen-2-one

Suppliers and Price of (R)-Marmin

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of (R)-Marmin

Chemical Property:

Vapor Pressure:3.81E-12mmHg at 25°C
Boiling Point:531.9°Cat760mmHg
Flash Point:188.8°C
PSA：79.90000
Density:1.193g/cm³
LogP:3.03010
XLogP3:3
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:7
Exact Mass:332.16237386
Heavy Atom Count:24
Complexity:494

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(=CCOC1=CC2=C(C=C1)C=CC(=O)O2)CCC(C(C)(C)O)O
Isomeric SMILES:C/C(=C\COC1=CC2=C(C=C1)C=CC(=O)O2)/CCC(C(C)(C)O)O

Technology Process of (R)-Marmin

There total 16 articles about (R)-Marmin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 21499-17-2
Epoxyaurapten

: 5980-09-6,14957-38-1,31946-96-0,32064-13-4,61347-54-4,130548-21-9
(6'R,2'E)-dihydroxy-6',7' dimethyl-3',7' octene-2' oxy-7 coumarine

Guidance literature:: With sulfuric acid; In tetrahydrofuran; for 2h; Ambient temperature;
DOI:10.1016/S0040-4020(01)85097-3

Reference yield:

: 5389-87-7
1-chloro-3,7-dimethylocta-2,6-diene

: 5980-09-6,14957-38-1,31946-96-0,32064-13-4,61347-54-4,130548-21-9
(6'R,2'E)-dihydroxy-6',7' dimethyl-3',7' octene-2' oxy-7 coumarine

Guidance literature:: Multi-step reaction with 3 steps

1: 73 percent / m-CPBA; K₂CO₃ / CH₂Cl₂ / 24 h / 0 °C

2: 10 percent / NaH / dimethylformamide / 12 h / 20 °C

3: Rhodococcus ruber DSM 43338 / H₂O; various solvent(s) / 216 h / pH 8.0

With Rhodococcus ruber DSM 43338; sodium hydride; potassium carbonate; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; water; N,N-dimethyl-formamide;
DOI:10.1016/j.tet.2003.10.106