N,N-bis(4-bromophenyl)-N',N'-bis(4-(2,4,4-trimethylpentan-2-yl)phenyl)-1,4-phenylenediamine

Base Information

Chemical Name:N,N-bis(4-bromophenyl)-N',N'-bis(4-(2,4,4-trimethylpentan-2-yl)phenyl)-1,4-phenylenediamine
CAS No.:1213714-81-8
Molecular Formula:C₄₆H₅₄Br₂N₂
Molecular Weight:794.756
Hs Code.:

Synonyms:N,N-bis(4-bromophenyl)-N',N'-bis(4-(2,4,4-trimethylpentan-2-yl)phenyl)-1,4-phenylenediamine

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Chemical Property of N,N-bis(4-bromophenyl)-N',N'-bis(4-(2,4,4-trimethylpentan-2-yl)phenyl)-1,4-phenylenediamine

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Technology Process of N,N-bis(4-bromophenyl)-N',N'-bis(4-(2,4,4-trimethylpentan-2-yl)phenyl)-1,4-phenylenediamine

There total 4 articles about N,N-bis(4-bromophenyl)-N',N'-bis(4-(2,4,4-trimethylpentan-2-yl)phenyl)-1,4-phenylenediamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

: 937041-74-2
N,N-bis[4-(1,1,3,3-tetramethylbutyl)phenyl]-p-phenylenediamine

: 589-87-7
1,4-bromoiodobenzene

: 1213714-81-8
N,N-bis(4-bromophenyl)-N',N'-bis(4-(2,4,4-trimethylpentan-2-yl)phenyl)-1,4-phenylenediamine

Guidance literature:: With 1,1'-bis-(diphenylphosphino)ferrocene; bis(dibenzylideneacetone)-palladium⁽⁰⁾; sodium t-butanolate; In toluene; for 6h; Inert atmosphere; Reflux;
DOI:10.1021/ma902138g

Reference yield:

: 937041-72-0
4-nitro-N,N-bis(4-(2,4,4-trimethylpentan-2-yl)phenyl)aniline

: 1213714-81-8
N,N-bis(4-bromophenyl)-N',N'-bis(4-(2,4,4-trimethylpentan-2-yl)phenyl)-1,4-phenylenediamine

Guidance literature:: Multi-step reaction with 2 steps

1: palladium 10% on activated carbon; hydrazine hydrate / ethanol / Inert atmosphere; Reflux

2: 1,1'-bis-(diphenylphosphino)ferrocene; bis(dibenzylideneacetone)-palladium⁽⁰⁾; sodium t-butanolate / toluene / 6 h / Inert atmosphere; Reflux

With 1,1'-bis-(diphenylphosphino)ferrocene; palladium 10% on activated carbon; hydrazine hydrate; bis(dibenzylideneacetone)-palladium⁽⁰⁾; sodium t-butanolate; In ethanol; toluene; 2: Buchwald-Hartwig reaction;
DOI:10.1021/ma902138g

Reference yield:

: 350-46-9,178603-76-4
4-Fluoronitrobenzene

: 1213714-81-8
N,N-bis(4-bromophenyl)-N',N'-bis(4-(2,4,4-trimethylpentan-2-yl)phenyl)-1,4-phenylenediamine

Guidance literature:: Multi-step reaction with 3 steps

1: sodium hydride / dimethyl sulfoxide / 48 h / 120 °C / Inert atmosphere

2: palladium 10% on activated carbon; hydrazine hydrate / ethanol / Inert atmosphere; Reflux

3: 1,1'-bis-(diphenylphosphino)ferrocene; bis(dibenzylideneacetone)-palladium⁽⁰⁾; sodium t-butanolate / toluene / 6 h / Inert atmosphere; Reflux

With 1,1'-bis-(diphenylphosphino)ferrocene; palladium 10% on activated carbon; sodium hydride; hydrazine hydrate; bis(dibenzylideneacetone)-palladium⁽⁰⁾; sodium t-butanolate; In ethanol; dimethyl sulfoxide; toluene; 3: Buchwald-Hartwig reaction;
DOI:10.1021/ma902138g