1,3-bis(2,6-diisopropylphenyl)-1,3-diaza-2-silacyclopent-4-en-2-ylidene

Base Information

• Chemical Name: 1,3-bis(2,6-diisopropylphenyl)-1,3-diaza-2-silacyclopent-4-en-2-ylidene
• CAS No.: 202754-32-3
• Molecular Formula: C₂₆H₃₆N₂Si
• Molecular Weight: 404.671
• Mol file: 202754-32-3.mol

Synonyms:1,3-bis(2,6-diisopropylphenyl)-1,3-diaza-2-silacyclopent-4-en-2-ylidene

Chemical Property of 1,3-bis(2,6-diisopropylphenyl)-1,3-diaza-2-silacyclopent-4-en-2-ylidene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,3-bis(2,6-diisopropylphenyl)-1,3-diaza-2-silacyclopent-4-en-2-ylidene

There total 5 articles about 1,3-bis(2,6-diisopropylphenyl)-1,3-diaza-2-silacyclopent-4-en-2-ylidene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

1,3-bis(2,6-diisopropylphenyl)-1,3-diaza-2,2-dichloro-2-silacyclopent-4-ene (198057-39-5) → 1,3-bis(2,6-diisopropylphenyl)-1,3-diaza-2-silacyclopent-4-en-2-ylidene (202754-32-3)

Guidance literature:

With lithium naphthalide; In tetrahydrofuran; at 20 ℃; for 20h;

DOI:10.1016/j.jorganchem.2009.10.034

Reference yield: 60.8%

C26H36Cl6N2Si2 → 1,3-bis(2,6-diisopropylphenyl)-1,3-diaza-2-silacyclopent-4-en-2-ylidene (202754-32-3)

Guidance literature:

With potassium graphite; In tetrahydrofuran; at -78 - -30 ℃;

DOI:10.1039/b905905a

Reference yield:

C38H74N2Si7 + 1,2-bis(2,6-diisopropylphenylimino)ethane (74663-75-5,134750-23-5) → 1,3-bis(2,6-diisopropylphenyl)-1,3-diaza-2-silacyclopent-4-en-2-ylidene (202754-32-3) + C45H73N3Si3

Guidance literature:

In benzene-d6; at 80 ℃; for 24h; Inert atmosphere; Sealed tube;

DOI:10.1021/jacs.1c06654

upstream raw materials:

1,3-bis(2,6-diisopropylphenyl)-1,3-diaza-2,2-dichloro-2-silacyclopent-4-ene

1,2-bis(2,6-diisopropylphenylimino)ethane

Downstream raw materials:

di-μ-sulfo-di-1,3-bis(2,6-diisopropylphenyl)-1,3-diaza-2-silacyclopent-4-en-2-ylidene

di-μ-seleno-di-1,3-bis(2,6-diisopropylphenyl)-1,3-diaza-2-silacyclopent-4-en-2-ylidene

di-μ-telluro-di-1,3-bis(2,6-diisopropylphenyl)-1,3-diaza-2-silacyclopent-4-en-2-ylidene

C₅₀H₆₁N₃Si