(1S,4S)-4-(tert-Butyl-dimethyl-silanyloxy)-1-{(S)-2-[(1S,2S)-2-(tert-butyl-dimethyl-silanyloxymethyl)-1-methyl-3-methylene-cyclohexyl]-1-methoxymethoxy-ethyl}-2,6,6-trimethyl-cyclohex-2-enol

Base Information

Chemical Name:(1S,4S)-4-(tert-Butyl-dimethyl-silanyloxy)-1-{(S)-2-[(1S,2S)-2-(tert-butyl-dimethyl-silanyloxymethyl)-1-methyl-3-methylene-cyclohexyl]-1-methoxymethoxy-ethyl}-2,6,6-trimethyl-cyclohex-2-enol
CAS No.:872315-28-1
Molecular Formula:C₃₄H₆₆O₅Si₂
Molecular Weight:611.066
Hs Code.:

(1S,4S)-4-(tert-Butyl-dimethyl-silanyloxy)-1-{(S)-2-[(1S,2S)-2-(tert-butyl-dimethyl-silanyloxymethyl)-1-methyl-3-methylene-cyclohexyl]-1-methoxymethoxy-ethyl}-2,6,6-trimethyl-cyclohex-2-enol

Synonyms:(1S,4S)-4-(tert-Butyl-dimethyl-silanyloxy)-1-{(S)-2-[(1S,2S)-2-(tert-butyl-dimethyl-silanyloxymethyl)-1-methyl-3-methylene-cyclohexyl]-1-methoxymethoxy-ethyl}-2,6,6-trimethyl-cyclohex-2-enol

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Chemical Property of (1S,4S)-4-(tert-Butyl-dimethyl-silanyloxy)-1-{(S)-2-[(1S,2S)-2-(tert-butyl-dimethyl-silanyloxymethyl)-1-methyl-3-methylene-cyclohexyl]-1-methoxymethoxy-ethyl}-2,6,6-trimethyl-cyclohex-2-enol

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Technology Process of (1S,4S)-4-(tert-Butyl-dimethyl-silanyloxy)-1-{(S)-2-[(1S,2S)-2-(tert-butyl-dimethyl-silanyloxymethyl)-1-methyl-3-methylene-cyclohexyl]-1-methoxymethoxy-ethyl}-2,6,6-trimethyl-cyclohex-2-enol

There total 1 articles about (1S,4S)-4-(tert-Butyl-dimethyl-silanyloxy)-1-{(S)-2-[(1S,2S)-2-(tert-butyl-dimethyl-silanyloxymethyl)-1-methyl-3-methylene-cyclohexyl]-1-methoxymethoxy-ethyl}-2,6,6-trimethyl-cyclohex-2-enol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: tert-Butyl-[(1S,2S)-2-((R)-2-methoxymethoxy-2-tributylstannanyl-ethyl)-2-methyl-6-methylene-cyclohexylmethoxy]-dimethyl-silane

: 169124-54-3
(S)-4-tert-butyldimethylsilyloxy-2,6,6-trimethyl-2-cyclohexenone

: 872315-28-1
(1S,4S)-4-(tert-Butyl-dimethyl-silanyloxy)-1-{(S)-2-[(1S,2S)-2-(tert-butyl-dimethyl-silanyloxymethyl)-1-methyl-3-methylene-cyclohexyl]-1-methoxymethoxy-ethyl}-2,6,6-trimethyl-cyclohex-2-enol

: 872315-29-2
(1R,4S)-4-(tert-Butyl-dimethyl-silanyloxy)-1-{(S)-2-[(1S,2S)-2-(tert-butyl-dimethyl-silanyloxymethyl)-1-methyl-3-methylene-cyclohexyl]-1-methoxymethoxy-ethyl}-2,6,6-trimethyl-cyclohex-2-enol

Guidance literature:: tert-Butyl-[(1S,2S)-2-((R)-2-methoxymethoxy-2-tributylstannanyl-ethyl)-2-methyl-6-methylene-cyclohexylmethoxy]-dimethyl-silane; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 0.166667h;

(S)-4-tert-butyldimethylsilyloxy-2,6,6-trimethyl-2-cyclohexenone; In tetrahydrofuran; at -78 ℃; for 0.333333h;
DOI:10.1016/j.tetasy.2005.09.012

Reference yield: 87.0%

: 872315-28-1
(1S,4S)-4-(tert-Butyl-dimethyl-silanyloxy)-1-{(S)-2-[(1S,2S)-2-(tert-butyl-dimethyl-silanyloxymethyl)-1-methyl-3-methylene-cyclohexyl]-1-methoxymethoxy-ethyl}-2,6,6-trimethyl-cyclohex-2-enol

: 872315-30-5
(1S,4S)-1-[(S)-2-((1S,2S)-2-Hydroxymethyl-1-methyl-3-methylene-cyclohexyl)-1-methoxymethoxy-ethyl]-2,6,6-trimethyl-cyclohex-2-ene-1,4-diol

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 60 ℃; for 2h;
DOI:10.1016/j.tetasy.2005.09.012

Reference yield:

: 872315-28-1
(1S,4S)-4-(tert-Butyl-dimethyl-silanyloxy)-1-{(S)-2-[(1S,2S)-2-(tert-butyl-dimethyl-silanyloxymethyl)-1-methyl-3-methylene-cyclohexyl]-1-methoxymethoxy-ethyl}-2,6,6-trimethyl-cyclohex-2-enol

: (1S,2S)-2-[(S)-2-((S)-1-Hydroxy-2,6,6-trimethyl-4-oxo-cyclohex-2-enyl)-2-methoxymethoxy-ethyl]-2-methyl-6-methylene-cyclohexanecarbaldehyde

Guidance literature:: Multi-step reaction with 2 steps

1: 87 percent / tetra-n-butylammonium fluoride / tetrahydrofuran / 2 h / 60 °C

2: 86 percent / Dess-Martin periodinane; pyridine / CH₂Cl₂ / 1.5 h / 25 °C

With pyridine; tetrabutyl ammonium fluoride; Dess-Martin periodane; In tetrahydrofuran; dichloromethane; 2: Dess-Martin oxidation;
DOI:10.1016/j.tetasy.2005.09.012