phenyl-2-amino-3,4,6-tri-O-benzyl-2-deoxy-1-seleno-α-D-galactopyranoside

Base Information

• Chemical Name: phenyl-2-amino-3,4,6-tri-O-benzyl-2-deoxy-1-seleno-α-D-galactopyranoside
• CAS No.: 190782-03-7
• Molecular Formula: C₃₃H₃₅NO₄Se
• Molecular Weight: 588.605
• Mol file: 190782-03-7.mol

Synonyms:phenyl-2-amino-3,4,6-tri-O-benzyl-2-deoxy-1-seleno-α-D-galactopyranoside

Chemical Property of phenyl-2-amino-3,4,6-tri-O-benzyl-2-deoxy-1-seleno-α-D-galactopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of phenyl-2-amino-3,4,6-tri-O-benzyl-2-deoxy-1-seleno-α-D-galactopyranoside

There total 3 articles about phenyl-2-amino-3,4,6-tri-O-benzyl-2-deoxy-1-seleno-α-D-galactopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

Phenyl 2-azido-3,4,6-tri-O-benzyl-2-deoxy-1-seleno-α-D-galactopyranoside (153808-91-4) → phenyl-2-amino-3,4,6-tri-O-benzyl-2-deoxy-1-seleno-α-D-galactopyranoside (190782-03-7)

Guidance literature:

With lithium aluminium tetrahydride; In diethyl ether; at 0 ℃; for 0.0833333h;

DOI:10.1016/S0957-4166(97)00141-9

Reference yield:

diphenyl diselenide (1666-13-3) → phenyl-2-amino-3,4,6-tri-O-benzyl-2-deoxy-1-seleno-α-D-galactopyranoside (190782-03-7)

Guidance literature:

Multi-step reaction with 2 steps

1: 43 percent / PhI(OAc)2, NaN₃ / CH₂Cl₂ / 20 h / Ambient temperature

2: 88 percent / LiAlH₄ / diethyl ether / 0.08 h / 0 °C

With lithium aluminium tetrahydride; sodium azide; [bis(acetoxy)iodo]benzene; In diethyl ether; dichloromethane;

DOI:10.1016/S0957-4166(97)00141-9

Reference yield:

3,4,6-tri-O-benzyl-D-galactal (80040-79-5) → phenyl-2-amino-3,4,6-tri-O-benzyl-2-deoxy-1-seleno-α-D-galactopyranoside (190782-03-7)

Guidance literature:

Multi-step reaction with 2 steps

1: 43 percent / PhI(OAc)2, NaN₃ / CH₂Cl₂ / 20 h / Ambient temperature

2: 88 percent / LiAlH₄ / diethyl ether / 0.08 h / 0 °C

With lithium aluminium tetrahydride; sodium azide; [bis(acetoxy)iodo]benzene; In diethyl ether; dichloromethane;

DOI:10.1016/S0957-4166(97)00141-9

upstream raw materials:

Phenyl 2-azido-3,4,6-tri-O-benzyl-2-deoxy-1-seleno-α-D-galactopyranoside

diphenyl diselenide

3,4,6-tri-O-benzyl-D-galactal

Downstream raw materials:

Phenyl 2-(N-acetylamino)-3,4,6-tri-O-benzyl-2-deoxy-1-seleno-α-D-galactopyranoside

C₆₁H₆₄NO₁₀PSe

C₆₁H₆₄NO₁₀PSe

2-acetamido-2-deoxy-3,4,6-tri-O-benzyl-D-galactopyranose