1-[4,6-di-O-(tert-butyldimethylsilyl)-2,3-dideoxy-β-D-erythro-hex-2-enopyranosyl]-4-n-butylbenzene

Base Information

Chemical Name:1-[4,6-di-O-(tert-butyldimethylsilyl)-2,3-dideoxy-β-D-erythro-hex-2-enopyranosyl]-4-n-butylbenzene
CAS No.:404872-01-1
Molecular Formula:C₂₈H₅₀O₃Si₂
Molecular Weight:490.874
Hs Code.:

Synonyms:1-[4,6-di-O-(tert-butyldimethylsilyl)-2,3-dideoxy-β-D-erythro-hex-2-enopyranosyl]-4-n-butylbenzene

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Chemical Property of 1-[4,6-di-O-(tert-butyldimethylsilyl)-2,3-dideoxy-β-D-erythro-hex-2-enopyranosyl]-4-n-butylbenzene

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Technology Process of 1-[4,6-di-O-(tert-butyldimethylsilyl)-2,3-dideoxy-β-D-erythro-hex-2-enopyranosyl]-4-n-butylbenzene

There total 1 articles about 1-[4,6-di-O-(tert-butyldimethylsilyl)-2,3-dideoxy-β-D-erythro-hex-2-enopyranosyl]-4-n-butylbenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 185416-14-2
4-(1-butyl)phenylmagnesium bromide

: 201232-73-7
p-tert-butylphenyl 4,6-di-O-tert-butyl(dimethyl)silyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranoside

: 404872-01-1
1-[4,6-di-O-(tert-butyldimethylsilyl)-2,3-dideoxy-β-D-erythro-hex-2-enopyranosyl]-4-n-butylbenzene

Guidance literature:: With 1,2-bis(diphenylphosphino)ethane nickel(II) chloride; In tetrahydrofuran; at -40 ℃; for 24h;

Reference yield: 90.0%

: 404872-01-1
1-[4,6-di-O-(tert-butyldimethylsilyl)-2,3-dideoxy-β-D-erythro-hex-2-enopyranosyl]-4-n-butylbenzene

: 404872-07-7
1-(2,3-dideoxy-β-D-erythro-hex-2-enopyranosyl)-4-n-butylbenzene

Guidance literature:: With tetrabutyl-ammonium chloride; In tetrahydrofuran; at 25 ℃; for 2h;

Reference yield:

: 404872-01-1
1-[4,6-di-O-(tert-butyldimethylsilyl)-2,3-dideoxy-β-D-erythro-hex-2-enopyranosyl]-4-n-butylbenzene

: (2R,4aR,6R,8aS)-6-(4-Butyl-phenyl)-2-(4-hexyloxy-phenyl)-hexahydro-pyrano[3,2-d][1,3]dioxine

Guidance literature:: Multi-step reaction with 3 steps

1: 90 percent / tetrabutylammonium chloride trihydrate / tetrahydrofuran / 2 h / 25 °C

2: 90 percent / H₂ / [Rh(COD)(1,4-bis(diphenylphosphino)butane)]ClO₄ / ethanol / 24 h / 20 °C / atmospheric pressure

3: p-toluenesulfonic acid monohydrate / dimethylformamide / 60 °C / 22.5 Torr

With tetrabutyl-ammonium chloride; hydrogen; toluene-4-sulfonic acid; [Rh(COD)(1,4-bis(diphenylphosphino)butane)]ClO₄; In tetrahydrofuran; ethanol; N,N-dimethyl-formamide;