acetylacetonato(22,23,72,73,122,123,172,173-octaphenyltetrapyrazino[b,g,l,q]-5,10,15,20-tetraazaporphyrinato)lutetium(III)

Base Information

Chemical Name:acetylacetonato(22,23,72,73,122,123,172,173-octaphenyltetrapyrazino[b,g,l,q]-5,10,15,20-tetraazaporphyrinato)lutetium(III)
CAS No.:1127415-21-7
Molecular Formula:C₅H₇O₂*C₇₂H₄₀N₁₆*Lu
Molecular Weight:1403.29
Hs Code.:

Synonyms:acetylacetonato(22,23,72,73,122,123,172,173-octaphenyltetrapyrazino[b,g,l,q]-5,10,15,20-tetraazaporphyrinato)lutetium(III)

Suppliers and Price of acetylacetonato(22,23,72,73,122,123,172,173-octaphenyltetrapyrazino[b,g,l,q]-5,10,15,20-tetraazaporphyrinato)lutetium(III)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of acetylacetonato(22,23,72,73,122,123,172,173-octaphenyltetrapyrazino[b,g,l,q]-5,10,15,20-tetraazaporphyrinato)lutetium(III)

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of acetylacetonato(22,23,72,73,122,123,172,173-octaphenyltetrapyrazino[b,g,l,q]-5,10,15,20-tetraazaporphyrinato)lutetium(III)

There total 1 articles about acetylacetonato(22,23,72,73,122,123,172,173-octaphenyltetrapyrazino[b,g,l,q]-5,10,15,20-tetraazaporphyrinato)lutetium(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: tris(acetylacetonato)-lutetium(III)

: 52197-23-6
5,6-diphenyl-pyrazine-2,3-dicarbonitrile

acetylacetonato(22,23,72,73,122,123,172,173-octaphenyltetrapyrazino[b,g,l,q]-5,10,15,20-tetraazaporphyrinato)lutetium(III): 1127415-21-7
acetylacetonato(22,23,72,73,122,123,172,173-octaphenyltetrapyrazino[b,g,l,q]-5,10,15,20-tetraazaporphyrinato)lutetium(III)

Guidance literature:: With sodium methylate; urea; In benzonitrile; mixt. of 0.66 mmol 5,6-diphenylpyrazine-2,3-dicarbonitrile and 0.16 mmolof metal complex, benzonitrile, 1.6 mmol of urea, catalytical amt. of M eONa heated to 160°C in quartz ampoule and kept at that temp. for1 h; hot filtered; solvent distd. off under vac.; residue purified by column chromy. on silica gel (DMF, 1:1 as eluent); elem. anal.;
DOI:10.1134/S1070363207110175

Reference yield:

acetylacetonato(22,23,72,73,122,123,172,173-octaphenyltetrapyrazino[b,g,l,q]-5,10,15,20-tetraazaporphyrinato)lutetium(III): 1127415-21-7
acetylacetonato(22,23,72,73,122,123,172,173-octaphenyltetrapyrazino[b,g,l,q]-5,10,15,20-tetraazaporphyrinato)lutetium(III)

: 7664-93-9
sulfuric acid

: CH₃COCHCOCH₃^(1-)*Lu⁽³⁺⁾*N₁₆C₂₄H(C₆H₅)8^(1-)=(CH₃COCHCOCH₃)Lu(N₁₆C₂₄H(C₆H₅)8)⁽¹⁺⁾

Guidance literature:: In acetic acid; H2SO4 (up to 2% in acetic acid) added to soln. of Lu complex in acetic acid at 298 K; not isolated, detected by UV-vis spectroscopy;
DOI:10.1134/S1070363207120183

Reference yield:

acetylacetonato(22,23,72,73,122,123,172,173-octaphenyltetrapyrazino[b,g,l,q]-5,10,15,20-tetraazaporphyrinato)lutetium(III): 1127415-21-7
acetylacetonato(22,23,72,73,122,123,172,173-octaphenyltetrapyrazino[b,g,l,q]-5,10,15,20-tetraazaporphyrinato)lutetium(III)

: 76-05-1
trifluoroacetic acid

: CH₃COCHCOCH₃^(1-)*Lu⁽³⁺⁾*N₁₆C₂₄H₂(C₆H₅)8=(CH₃COCHCOCH₃)Lu(N₁₆C₂₄H₂(C₆H₅)8)⁽²⁺⁾

Guidance literature:: In dichloromethane; CF3COOH added to soln. of Lu complex in CH2Cl2 at 298 K; not isolated, detected by UV-vis spectroscopy;
DOI:10.1134/S1070363207120183