ethyl (2R)-2-(tert-butoxycarbonylamino)-4-(phenylsulfanyl)pent-4-enoate

Base Information

• Chemical Name: ethyl (2R)-2-(tert-butoxycarbonylamino)-4-(phenylsulfanyl)pent-4-enoate
• CAS No.: 885219-39-6
• Molecular Formula: C₁₈H₂₅NO₄S
• Molecular Weight: 351.467
• Mol file: 885219-39-6.mol

Synonyms:ethyl (2R)-2-(tert-butoxycarbonylamino)-4-(phenylsulfanyl)pent-4-enoate

Chemical Property of ethyl (2R)-2-(tert-butoxycarbonylamino)-4-(phenylsulfanyl)pent-4-enoate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of ethyl (2R)-2-(tert-butoxycarbonylamino)-4-(phenylsulfanyl)pent-4-enoate

There total 1 articles about ethyl (2R)-2-(tert-butoxycarbonylamino)-4-(phenylsulfanyl)pent-4-enoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

CH2CSC6H5CH2Si(CH3)3 + [(E)-tert-Butoxycarbonylimino]-acetic acid ethyl ester (81357-11-1) → ethyl (2R)-2-(tert-butoxycarbonylamino)-4-(phenylsulfanyl)pent-4-enoate (885219-39-6) + ethyl (2S)-2-(tert-butoxycarbonylamino)-4-(phenylsulfanyl)pent-4-enoate

Guidance literature:

With copper(II) bis(trifluoromethanesulfonate); In dichloromethane; toluene; at 0 ℃; for 0.75h;

DOI:10.1002/anie.200504196

Reference yield: 71.0%

ethyl (2R)-2-(tert-butoxycarbonylamino)-4-(phenylsulfanyl)pent-4-enoate (885219-39-6) → ethyl (2R)-2-(tert-butoxycarbonylamino)-4-(phenylsulfinyl)pent-4-enoate

Guidance literature:

With dihydrogen peroxide; In methanol; at 20 ℃; for 24h;

DOI:10.1002/anie.200504196

Reference yield:

ethyl (2R)-2-(tert-butoxycarbonylamino)-4-(phenylsulfanyl)pent-4-enoate (885219-39-6) → ethyl (2R)-2-(tert-butoxycarbonylamino)-4-(phenylsulfonyl)hexanoate

Guidance literature:

ethyl (2R)-2-(tert-butoxycarbonylamino)-4-(phenylsulfanyl)pent-4-enoate; With 3-chloro-benzenecarboperoxoic acid; In toluene; at 20 ℃; for 24h;

Me₂CuLi; In diethyl ether; at 0 ℃; for 0.0833333h; Further stages.;

DOI:10.1002/anie.200504196

upstream raw materials:

[(E)-tert-Butoxycarbonylimino]-acetic acid ethyl ester