1,1'-<<(hexane-1,6-diyl)dioxy>bis<(2-nitro-5-methoxy-1,4-phenylene)carbonyl>>bis

Base Information

Chemical Name:1,1'-<<(hexane-1,6-diyl)dioxy>bis<(2-nitro-5-methoxy-1,4-phenylene)carbonyl>>bis
CAS No.:145325-52-6
Molecular Formula:C₄₀H₅₈N₄O₁₀S₄
Molecular Weight:883.185
Hs Code.:

1,1'-<<(hexane-1,6-diyl)dioxy>bis<(2-nitro-5-methoxy-1,4-phenylene)carbonyl>>bis<pyrrolidine-2-carboxaldehyde diethyl dithioacetal>

Synonyms:1,1'-<<(hexane-1,6-diyl)dioxy>bis<(2-nitro-5-methoxy-1,4-phenylene)carbonyl>>bis

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Chemical Property of 1,1'-<<(hexane-1,6-diyl)dioxy>bis<(2-nitro-5-methoxy-1,4-phenylene)carbonyl>>bis

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Technology Process of 1,1'-<<(hexane-1,6-diyl)dioxy>bis<(2-nitro-5-methoxy-1,4-phenylene)carbonyl>>bis

There total 6 articles about 1,1'-<<(hexane-1,6-diyl)dioxy>bis<(2-nitro-5-methoxy-1,4-phenylene)carbonyl>>bis which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 105089-88-1
(2S)-2-[di(ethylsulfanyl)methyl]tetrahydro-1H-pyrrole

: 145325-49-1
1',6'-bis(4-carboxy-2-methoxy-5-nitrophenoxy)hexane

: 145325-52-6
1,1'-<<(hexane-1,6-diyl)dioxy>bis<(2-nitro-5-methoxy-1,4-phenylene)carbonyl>>bis

Guidance literature:: With oxalyl dichloride; water; triethylamine; In tetrahydrofuran; for 4h;
DOI:10.1039/c39920001518

Reference yield:

: 145325-43-5
1',6'-bis<2-methoxy-(4-methoxycarbonyl)phenoxy>hexane

: 145325-52-6
1,1'-<<(hexane-1,6-diyl)dioxy>bis<(2-nitro-5-methoxy-1,4-phenylene)carbonyl>>bis

Guidance literature:: Multi-step reaction with 3 steps

1: 65 percent / SnCl₄, HNO₃ / CH₂Cl₂ / 0.25 h / -25 °C

2: 90 percent / NaOH / tetrahydrofuran; H₂O / 6 h / 40 °C

3: 1) oxalyl chloride, DMF, 2) Et₃N / 1) THF, 4 h, 2) THF, H₂O, 0 deg C -> room temperature; room temperature, 1.5 h

With sodium hydroxide; oxalyl dichloride; nitric acid; tin(IV) chloride; triethylamine; N,N-dimethyl-formamide; In tetrahydrofuran; dichloromethane; water;
DOI:10.1021/jo951631s

Reference yield:

: 145325-46-8
1',6'-bis<2-methoxy-(4-methoxycarbonyl)-5-nitrophenoxy>hexane

: 145325-52-6
1,1'-<<(hexane-1,6-diyl)dioxy>bis<(2-nitro-5-methoxy-1,4-phenylene)carbonyl>>bis

Guidance literature:: Multi-step reaction with 2 steps

1: 90 percent / NaOH / tetrahydrofuran; H₂O / 6 h / 40 °C

2: 1) oxalyl chloride, DMF, 2) Et₃N / 1) THF, 4 h, 2) THF, H₂O, 0 deg C -> room temperature; room temperature, 1.5 h

With sodium hydroxide; oxalyl dichloride; triethylamine; N,N-dimethyl-formamide; In tetrahydrofuran; water;
DOI:10.1021/jo951631s