2-(4-(2-iodophenyl)butyl)-3-oxocyclohex-1-enyl trifluoromethanesulfonate

Base Information

Chemical Name:2-(4-(2-iodophenyl)butyl)-3-oxocyclohex-1-enyl trifluoromethanesulfonate
CAS No.:1271193-11-3
Molecular Formula:C₁₇H₁₈F₃IO₄S
Molecular Weight:502.293
Hs Code.:

Synonyms:2-(4-(2-iodophenyl)butyl)-3-oxocyclohex-1-enyl trifluoromethanesulfonate

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Chemical Property of 2-(4-(2-iodophenyl)butyl)-3-oxocyclohex-1-enyl trifluoromethanesulfonate

Chemical Property:

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Technology Process of 2-(4-(2-iodophenyl)butyl)-3-oxocyclohex-1-enyl trifluoromethanesulfonate

There total 8 articles about 2-(4-(2-iodophenyl)butyl)-3-oxocyclohex-1-enyl trifluoromethanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 358-23-6
trifluoromethylsulfonic anhydride

: C₁₆H₁₉IO₂

: 1271193-11-3
2-(4-(2-iodophenyl)butyl)-3-oxocyclohex-1-enyl trifluoromethanesulfonate

Guidance literature:: With pyridine; In dichloromethane; at -78 - 20 ℃;
DOI:10.1021/ol2003308

Reference yield:

: 1093413-28-5
4-(o-iodophenyl)butan-1-ol

: 1271193-11-3
2-(4-(2-iodophenyl)butyl)-3-oxocyclohex-1-enyl trifluoromethanesulfonate

Guidance literature:: Multi-step reaction with 3 steps

1.1: oxalyl dichloride; dimethyl sulfoxide / dichloromethane / 0.5 h / -78 °C

1.2: -78 - 20 °C

2.1: L-proline / ethanol / 20 °C

2.2: 85 °C / Molecular sieve

3.1: pyridine / dichloromethane / -78 - 20 °C

With pyridine; oxalyl dichloride; dimethyl sulfoxide; L-proline; In ethanol; dichloromethane;
DOI:10.1021/ol2003308

Reference yield:

: 26059-40-5
2-(2-iodophenyl)ethan-1-ol

: 1271193-11-3
2-(4-(2-iodophenyl)butyl)-3-oxocyclohex-1-enyl trifluoromethanesulfonate

Guidance literature:: Multi-step reaction with 7 steps

1.1: 1H-imidazole; iodine; triphenylphosphine / dichloromethane / 0 - 20 °C

2.1: sodium hydride / 0 - 20 °C

2.2: 20 °C

2.3: 150 °C

3.1: water; sodium chloride / dimethyl sulfoxide / 150 °C

4.1: diisobutylaluminium hydride / tetrahydrofuran; toluene / -50 °C

5.1: oxalyl dichloride; dimethyl sulfoxide / dichloromethane / 0.5 h / -78 °C

5.2: -78 - 20 °C

6.1: L-proline / ethanol / 20 °C

6.2: 85 °C / Molecular sieve

7.1: pyridine / dichloromethane / -78 - 20 °C

With pyridine; 1H-imidazole; oxalyl dichloride; water; iodine; sodium hydride; diisobutylaluminium hydride; dimethyl sulfoxide; triphenylphosphine; L-proline; sodium chloride; In tetrahydrofuran; ethanol; dichloromethane; dimethyl sulfoxide; toluene;
DOI:10.1021/ol2003308