Technology Process of CH3CNC6H4(CH2NCH2C6H5CC6H5C3HCH3N2(CH2)3)2Fe(2+)*2PF6(1-)=(CH3CNC6H4(CH2NCH2C6H5CC6H5C3HCH3N2(CH2)3)2Fe)(PF6)2
There total 1 articles about CH3CNC6H4(CH2NCH2C6H5CC6H5C3HCH3N2(CH2)3)2Fe(2+)*2PF6(1-)=(CH3CNC6H4(CH2NCH2C6H5CC6H5C3HCH3N2(CH2)3)2Fe)(PF6)2 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
triethylamine; acetonitrile;
In
acetonitrile;
ligand and slight excess of Fe complex slurring in MeCN; large excess of Et3N adding, refluxing for 5 min, cooling and filtering through celite, solvent removing, residue dissolving in hot MeOH, stirring for 10 min,filtering; purified by recrystn. from MeCN/EtOH or MeOH; identified by elem. anal.;
DOI:10.1021/ja00360a008