methyl 1,6-dideoxy-1-<3,4-dihydro-5-(methoxycarbonyl)-2,4-dioxo-1(2H)-pyrimidinyl>-5-O-(phenylmethyl)-L-glycero-β-allo-octofuranuronate 7-methanesulfonate

Base Information

Chemical Name:methyl 1,6-dideoxy-1-<3,4-dihydro-5-(methoxycarbonyl)-2,4-dioxo-1(2H)-pyrimidinyl>-5-O-(phenylmethyl)-L-glycero-β-allo-octofuranuronate 7-methanesulfonate
CAS No.:101696-61-1
Molecular Formula:C₂₃H₂₈N₂O₁₃S
Molecular Weight:572.547
Hs Code.:

methyl 1,6-dideoxy-1-<3,4-dihydro-5-(methoxycarbonyl)-2,4-dioxo-1(2H)-pyrimidinyl>-5-O-(phenylmethyl)-L-glycero-β-allo-octofuranuronate 7-methanesulfonate

Synonyms:methyl 1,6-dideoxy-1-<3,4-dihydro-5-(methoxycarbonyl)-2,4-dioxo-1(2H)-pyrimidinyl>-5-O-(phenylmethyl)-L-glycero-β-allo-octofuranuronate 7-methanesulfonate

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Chemical Property of methyl 1,6-dideoxy-1-<3,4-dihydro-5-(methoxycarbonyl)-2,4-dioxo-1(2H)-pyrimidinyl>-5-O-(phenylmethyl)-L-glycero-β-allo-octofuranuronate 7-methanesulfonate

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Technology Process of methyl 1,6-dideoxy-1-<3,4-dihydro-5-(methoxycarbonyl)-2,4-dioxo-1(2H)-pyrimidinyl>-5-O-(phenylmethyl)-L-glycero-β-allo-octofuranuronate 7-methanesulfonate

There total 16 articles about methyl 1,6-dideoxy-1-<3,4-dihydro-5-(methoxycarbonyl)-2,4-dioxo-1(2H)-pyrimidinyl>-5-O-(phenylmethyl)-L-glycero-β-allo-octofuranuronate 7-methanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 101696-60-0
methyl 1,6-dideoxy-1-<3,4-dihydro-5-(methoxycarbonyl)-2,4-dioxo-1(2H)-pyrimidinyl>-5-O-(phenylmethyl)-L-glycero-β-allo-octofuranuronate 2,3-diacetate 7-methanesulfonate

: 101696-61-1
methyl 1,6-dideoxy-1-<3,4-dihydro-5-(methoxycarbonyl)-2,4-dioxo-1(2H)-pyrimidinyl>-5-O-(phenylmethyl)-L-glycero-β-allo-octofuranuronate 7-methanesulfonate

Guidance literature:: With methanol; sodium methylate; for 1.5h;
DOI:10.1021/ja00230a024

Reference yield:

: (2R,4R)-4-Benzyloxy-4-((2R,3R,4R)-3,4-diacetoxy-5-methoxy-tetrahydro-furan-2-yl)-2-methanesulfonyloxy-butyric acid methyl ester

: 101696-61-1
methyl 1,6-dideoxy-1-<3,4-dihydro-5-(methoxycarbonyl)-2,4-dioxo-1(2H)-pyrimidinyl>-5-O-(phenylmethyl)-L-glycero-β-allo-octofuranuronate 7-methanesulfonate

Guidance literature:: Multi-step reaction with 3 steps

1: 75 percent / H₂SO₄ / CH₂Cl₂

2: 91 percent / TMSOTf

3: 81 percent / NaOMe / methanol

With sulfuric acid; sodium methylate; trimethylsilyl trifluoromethanesulfonate; In methanol; dichloromethane;
DOI:10.1021/ja00269a080

Reference yield:

: (2R,4R)-4-Benzyloxy-2-methanesulfonyloxy-4-((2R,3R,4R)-3,4,5-triacetoxy-tetrahydro-furan-2-yl)-butyric acid methyl ester

: 101696-61-1
methyl 1,6-dideoxy-1-<3,4-dihydro-5-(methoxycarbonyl)-2,4-dioxo-1(2H)-pyrimidinyl>-5-O-(phenylmethyl)-L-glycero-β-allo-octofuranuronate 7-methanesulfonate

Guidance literature:: Multi-step reaction with 2 steps

1: 91 percent / TMSOTf

2: 81 percent / NaOMe / methanol

With sodium methylate; trimethylsilyl trifluoromethanesulfonate; In methanol;
DOI:10.1021/ja00269a080