C₁₁₄H₁₈₀Cl₄O₂₅Si₄

Base Information

• Chemical Name: C₁₁₄H₁₈₀Cl₄O₂₅Si₄
• CAS No.: 392692-71-6
• Molecular Formula: C₁₁₄H₁₈₀Cl₄O₂₅Si₄
• Molecular Weight: 2204.82
• Mol file: 392692-71-6.mol

Synonyms:C₁₁₄H₁₈₀Cl₄O₂₅Si₄

Chemical Property of C₁₁₄H₁₈₀Cl₄O₂₅Si₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of C₁₁₄H₁₈₀Cl₄O₂₅Si₄

There total 1 articles about C₁₁₄H₁₈₀Cl₄O₂₅Si₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

C51H85Cl3O15Si2 (218799-04-3) + C81H111ClO11PSi2(1+)*I(1-) → C114H180Cl4O25Si4 (392692-71-6)

Guidance literature:

C₈₁H₁₁₁ClO₁₁PSi₂⁽¹⁺⁾*I^(1-); With N,N,N,N,N,N-hexamethylphosphoric triamide; lithium hexamethyldisilazane; In tetrahydrofuran; at -78 ℃; for 0.166667h;

C₅₁H₈₅Cl₃O₁₅Si₂; at -78 - -20 ℃; for 0.666667h;

DOI:10.1002/1521-3773(20011105)40:21<4055::AID-ANIE4055>3.0.CO;2-H

Reference yield:

C114H180Cl4O25Si4 (392692-71-6) → (+)-spongistatin 1 (149715-96-8)

Guidance literature:

Multistep reaction;

DOI:10.1002/1521-3773(20011105)40:21<4055::AID-ANIE4055>3.0.CO;2-H

Reference yield:

C114H180Cl4O25Si4 (392692-71-6) → (+)-spongistatin 1 (149715-96-8) + C63H93ClO20

Guidance literature:

Multistep reaction;

DOI:10.1039/b504151a

upstream raw materials:

C₅₁H₈₅Cl₃O₁₅Si₂

Downstream raw materials:

(+)-spongistatin 1

Refernces

• 1、 Paterson, Ian,Chen, David Y.-K.,Coster, Mark J.,Acena, Jose L.,Bach, Jordi,Wallace, Debra J.. "The stereocontrolled total synthesis of altohyrtin A/spongistatin 1: Fragment couplings, completion of the synthesis, analogue generation and biological evaluation". . p. 2431 - 2440. Retrieved 2007/10/03.