phenylmethyl-n-butylsulfonium fluoroborate

Base Information

• Chemical Name: phenylmethyl-n-butylsulfonium fluoroborate
• CAS No.: 82135-73-7
• Molecular Formula: BF₄*C₁₁H₁₇S
• Molecular Weight: 268.127
• Mol file: 82135-73-7.mol

Synonyms:phenylmethyl-n-butylsulfonium fluoroborate

Chemical Property of phenylmethyl-n-butylsulfonium fluoroborate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of phenylmethyl-n-butylsulfonium fluoroborate

There total 3 articles about phenylmethyl-n-butylsulfonium fluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

(n-butylthio)benzene (1126-80-3) + trimethoxonium tetrafluoroborate (420-37-1) → phenylmethyl-n-butylsulfonium fluoroborate (82135-73-7)

Guidance literature:

In dichloromethane; for 0.25h;

DOI:10.1021/ja00380a020

Reference yield:

5-bromo-1-phenylsulfanylpentane (21782-59-2) → phenylmethyl-n-butylsulfonium fluoroborate (82135-73-7)

Guidance literature:

Multi-step reaction with 3 steps

1: 42 percent / AgPF₆

2: potassium in graphite / tetrahydrofuran / 1 h / Ambient temperature

3: 98 percent / CH₂Cl₂ / 0.25 h

With silver(I) hexafluorophosphate; potassium graphite; In tetrahydrofuran; dichloromethane;

DOI:10.1021/ja00380a020

Reference yield:

phenylpentamethylenesulfonium hexafluorophosphate (82135-89-5) → phenylmethyl-n-butylsulfonium fluoroborate (82135-73-7)

Guidance literature:

Multi-step reaction with 2 steps

1: potassium in graphite / tetrahydrofuran / 1 h / Ambient temperature

2: 98 percent / CH₂Cl₂ / 0.25 h

With potassium graphite; In tetrahydrofuran; dichloromethane;

DOI:10.1021/ja00380a020

upstream raw materials:

(n-butylthio)benzene

trimethoxonium tetrafluoroborate

5-bromo-1-phenylsulfanylpentane

phenylpentamethylenesulfonium hexafluorophosphate

Downstream raw materials:

(n-butylthio)benzene

methyl-phenyl-thioether