2-(2,6-diisopropylanilino)-7-p-methoxyphenyltropone

Base Information

• Chemical Name: 2-(2,6-diisopropylanilino)-7-p-methoxyphenyltropone
• CAS No.: 704902-72-7
• Molecular Formula: C₂₆H₂₉NO₂
• Molecular Weight: 387.522
• Mol file: 704902-72-7.mol

Synonyms:2-(2,6-diisopropylanilino)-7-p-methoxyphenyltropone

Chemical Property of 2-(2,6-diisopropylanilino)-7-p-methoxyphenyltropone

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of 2-(2,6-diisopropylanilino)-7-p-methoxyphenyltropone

There total 1 articles about 2-(2,6-diisopropylanilino)-7-p-methoxyphenyltropone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

2,6-diisopropylbenzenamine (24544-04-5) + 2-triflato-7-p-methoxyphenyltropone → 2-(2,6-diisopropylanilino)-7-p-methoxyphenyltropone (704902-72-7)

Guidance literature:

With tris(dibenzylideneacetone)dipalladium ⁽⁰⁾; caesium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; In toluene; at 90 ℃; for 20h;

DOI:10.1021/ja030634g

Reference yield: 63.0%

bis(triphenylphosphine)nickel phenyl chloride + 2-(2,6-diisopropylanilino)-7-p-methoxyphenyltropone (704902-72-7) → [(7-p-methoxyphenyl-2-(2,6-diisopropyl)anilinotropone)Ni(triphenylphosphine)(Ph)] (704902-80-7)

Guidance literature:

With sodium hydride; In tetrahydrofuran; charging of Schlenk tube with 2-(2,6-diisopropylanilino)-7-p-methoxyphenyltropone (1 equiv.) and NaH (5 equiv.) under Ar; addn. of THF; stirringfor 18 h; addn. of (PPh3)2Ni(Ph)Cl (1 equiv.); stirring for 1 h; filtration through Celite; removal of solvent in vac., recrystn. from toluene and pentane; elem. anal.;

DOI:10.1021/ja030634g

upstream raw materials:

2,6-diisopropylbenzenamine

Downstream raw materials:

[(7-p-methoxyphenyl-2-(2,6-diisopropyl)anilinotropone)Ni(triphenylphosphine)(Ph)]