(+/-)-(1RS,2SR)-5,5-ethylenedithio-2-<2-(2-methoxyphenyl)ethyl>-1,3,3-trimethylcyclohexanecarbaldehyde

Base Information

Chemical Name:(+/-)-(1RS,2SR)-5,5-ethylenedithio-2-<2-(2-methoxyphenyl)ethyl>-1,3,3-trimethylcyclohexanecarbaldehyde
CAS No.:110654-72-3
Molecular Formula:C₂₁H₃₀O₂S₂
Molecular Weight:378.6
Hs Code.:

Synonyms:(+/-)-(1RS,2SR)-5,5-ethylenedithio-2-<2-(2-methoxyphenyl)ethyl>-1,3,3-trimethylcyclohexanecarbaldehyde

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Chemical Property of (+/-)-(1RS,2SR)-5,5-ethylenedithio-2-<2-(2-methoxyphenyl)ethyl>-1,3,3-trimethylcyclohexanecarbaldehyde

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Technology Process of (+/-)-(1RS,2SR)-5,5-ethylenedithio-2-<2-(2-methoxyphenyl)ethyl>-1,3,3-trimethylcyclohexanecarbaldehyde

There total 4 articles about (+/-)-(1RS,2SR)-5,5-ethylenedithio-2-<2-(2-methoxyphenyl)ethyl>-1,3,3-trimethylcyclohexanecarbaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 90122-59-1
4-<2-(2-methoxyphenyl)ethyl>-3,5,5-trimethylcyclohex-2-enone

: 110654-72-3
(+/-)-(1RS,2SR)-5,5-ethylenedithio-2-<2-(2-methoxyphenyl)ethyl>-1,3,3-trimethylcyclohexanecarbaldehyde

Guidance literature:: Multi-step reaction with 3 steps

1: 71 percent / triethylaluminium / tetrahydrofuran / 22 h / Ambient temperature

2: 92 percent / boron trifluoride-diethyl ether / CH₂Cl₂ / 5 h / Ambient temperature

3: 1.) DIBAL; 2.) aq. HCl / 1.) DME, reflux, 2 h; 2.) reflux, 2 h.

With hydrogenchloride; boron trifluoride diethyl etherate; triethylaluminum; diisobutylaluminium hydride; In tetrahydrofuran; dichloromethane;

Reference yield:

: 31225-15-7
2-methoxybenzylmagnesium bromide

: 110654-72-3
(+/-)-(1RS,2SR)-5,5-ethylenedithio-2-<2-(2-methoxyphenyl)ethyl>-1,3,3-trimethylcyclohexanecarbaldehyde

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) copper(I)bromide; 2.) aq. HCl / 1.) diethyl ether, THF, 0 deg C; rt, 0.5 h; 2.)THF, reflux, 2 h.

2: 71 percent / triethylaluminium / tetrahydrofuran / 22 h / Ambient temperature

3: 92 percent / boron trifluoride-diethyl ether / CH₂Cl₂ / 5 h / Ambient temperature

4: 1.) DIBAL; 2.) aq. HCl / 1.) DME, reflux, 2 h; 2.) reflux, 2 h.

With hydrogenchloride; boron trifluoride diethyl etherate; triethylaluminum; diisobutylaluminium hydride; copper(I) bromide; In tetrahydrofuran; dichloromethane;

Reference yield:

: 90122-60-4,92830-58-5,92830-59-6,110654-69-8
(+/-)-(1RS,2SR)-2-<2-(2-methoxyphenyl)-ethyl>-1,3,3-trimethyl-5-oxocyclohexanecarbonitrile

: 110654-72-3
(+/-)-(1RS,2SR)-5,5-ethylenedithio-2-<2-(2-methoxyphenyl)ethyl>-1,3,3-trimethylcyclohexanecarbaldehyde

Guidance literature:: Multi-step reaction with 2 steps

1: 92 percent / boron trifluoride-diethyl ether / CH₂Cl₂ / 5 h / Ambient temperature

2: 1.) DIBAL; 2.) aq. HCl / 1.) DME, reflux, 2 h; 2.) reflux, 2 h.

With hydrogenchloride; boron trifluoride diethyl etherate; diisobutylaluminium hydride; In dichloromethane;